SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
Synonym(s):1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt;Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium
- CAS NO.：35789-01-6
- Empirical Formula: C6H19NSi2Sm
- Molecular Weight: 311.76
- MDL number: MFCD03427097
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-05-28 06:10:29
What is SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)?
The Uses of SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
Reactant for synthesis of:
- Heterobimetallic samarium(III) complexes
- Binuclear lanthanide complexes
Catalyst for:
- Coordination polymerization of renewable butyrolactone-based vinyl monomers
- Intramolecular hydroamination of non-activated alkenes
- Chiral functionalization of isoxazoles
- Enantioselective hydroamination / cyclization
Properties of SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
| Melting point: | 93-106 °C(lit.) |
| Boiling point: | 83-4°C/1x10-4mmHg |
| Flash point: | 36 °F |
| form | solid |
Safety information for SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Corrosion Corrosives GHS05 |
| GHS Hazard Statements |
H228:Flammable solids H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P231+P232:Handle under inert gas. Protect from moisture. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
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