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HomeProduct name listSAMARIUM TRIS(HEXAMETHYLDISILAZIDE)

SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)

Synonym(s):1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt;Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium

SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Structural

What is SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)?

The Uses of SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)

Reactant for synthesis of:

  • Heterobimetallic samarium(III) complexes
  • Binuclear lanthanide complexes

Catalyst for:
  • Coordination polymerization of renewable butyrolactone-based vinyl monomers
  • Intramolecular hydroamination of non-activated alkenes
  • Chiral functionalization of isoxazoles
  • Enantioselective hydroamination / cyclization

Properties of SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)

Melting point: 93-106 °C(lit.)
Boiling point: 83-4°C/1x10-4mmHg
Flash point: 36 °F
form  solid

Safety information for SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Corrosion
Corrosives
GHS05
GHS Hazard Statements H228:Flammable solids
H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases
H314:Skin corrosion/irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P231+P232:Handle under inert gas. Protect from moisture.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)

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