SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
Synonym(s):1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt;Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium
- CAS NO.：35789-01-6
- Empirical Formula: C6H19NSi2Sm
- Molecular Weight: 311.76
- MDL number: MFCD03427097
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-01-13 11:27:03
What is SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)?
The Uses of SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
Reactant for synthesis of:
- Heterobimetallic samarium(III) complexes
- Binuclear lanthanide complexes
Catalyst for:
- Coordination polymerization of renewable butyrolactone-based vinyl monomers
- Intramolecular hydroamination of non-activated alkenes
- Chiral functionalization of isoxazoles
- Enantioselective hydroamination / cyclization
Properties of SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
| Melting point: | 93-106 °C(lit.) |
| Boiling point: | 83-4°C/1x10-4mmHg |
| Flash point: | 36 °F |
| form | solid |
Safety information for SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Corrosion Corrosives GHS05 |
| GHS Hazard Statements |
H228:Flammable solids H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P231+P232:Handle under inert gas. Protect from moisture. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for SAMARIUM TRIS(HEXAMETHYLDISILAZIDE)
New Products
3-AMINO-3-(2-FLUORO-PHENYL)-PROPIONIC ACID Pentadecanoic acid Hendecanoic acid 2-AMINO-3-METHYLQUINOLINE HYDROCHLORIDE 3-Hydroxypropionitrile DL-3-Amino-3-(2-methoxyphenyl)propionic acid 5-Bromo-2-Fluoropyridine 2,3-Diamino-5-Chloropyridine 2-Amino-3-Hydroxypyridine 2,6-Diamino Pyridine 4-Amino-2-Chloropyridine 2-Hydroxy-4-Picoline 4-(4-(Dimethylamino)-1-(4-fluorophenyl)-1-hydroxybutyl)-3-(hydroxymethyl)benzonitrile 4-Bromo-3-(ethoxymethyl)benzoic acid 2,4-Dichloro-5-methoxyaniline 4,6-Dichloro-2-(propylthio)pyrimidin-5-amine N2-Isobutyryl-2'-O-methylguanosine 2-chloro-5-methylpyridin-4-amine 4-Bromobenzaldehyde 2-Chloro-6-nitro benzothiazole 2-Amino-4-phenyl-thiazole 4-Chloro-2-methyl quinoline 2-(Chloromethyl) quinazolin-4(3H)-one 5-Phenyl-[1,3,4]-thiadiazol-2-amineRelated products of tetrahydrofuran
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