CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Synonym(s):1,5-Cyclooctadiene, ruthenium complex;Chloro(1,5-cyclooctadiene)(η⁵-pentamethylcyclopentadienyl)ruthenium;Chloro(1,5-cyclooctadiene)(pentamethylcyclopentadienyl)ruthenium;Cp*RuCl(cod)

CAS NO.：92390-26-6
Empirical Formula: C18H27ClRu5*
Molecular Weight: 379.93
MDL number: MFCD07369035
SAFETY DATA SHEET (SDS)
Update Date: 2025-07-29 17:05:30

CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II) Structural

What is CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)?

The Uses of CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Chloro(pentamethylcyclopentadienyl)(cyclooctadiene)ruthenium(II) is a homogeneous catalyst for the formation of carbon-carbon and carbon-heteroatom bonds.
It can be used:

To catalyze cyclotrimerization of alkynylboronates, propargyl alcohols, and terminal alkynes to form arylboronate, which in turn undergoes palladium(II)-catalyzed carbonylation to form highly substituted phthalides.
To catalyze C-C coupling of norbornenes and norbornadiene with alkynes?to form [2 + 2] cycloadducts.
In combination with 2-diphenylphosphinoethylamine-potassium tertiary butoxide to form a ternary catalyst system that can catalyze fast racemization of chiral non-racemic sec-alcohols.
To synthesize new organoruthenium complexes with phosphorus-based ligands such as bis(phosphino)amines.
To catalyze the addition of organic disulfides to alkenes leading to vic-dithioethers.

Properties of CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Melting point:	143-147℃
storage temp.	-20°C
color	brown microxtls
Stability:	store cold

Safety information for CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

Signal word	Danger
Pictogram(s)	Flame Flammables GHS02
GHS Hazard Statements	H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases
Precautionary Statement Codes	P231+P232:Handle under inert gas. Protect from moisture. P422:Store contents under …

Computed Descriptors for CHLORO(1,5-CYCLOOCTADIENE)(PENTAMETHYLCYCLOPENTADIENYL)RUTHENIUM (II)

InChIKey

JBVMVFXUVNUNNG-ONEVTFJLSA-M

New Products

Boc-N-Me-Val-OH tert-butyl 9-methoxy-3-azaspiro[5.5]undecane-3-carboxylate Indole Methyl Resin Gabapentin EP Impurity B Ethyl N-(2- cyanoacetyl)carbamate Magnessium Ascorbate 1-Chloro-4-Methyl-2-Nitrobenzene 1,3-Diethyl-1,3-Diphenylurea 3-(4-morpholinophenylamino)-5-amino-1H-pyrazole-4-carbonitrile Methyl 2-methylquinoline-6-carboxylate 2,4-dihydroxybenzaldehyde 2-((4-morpholinophenylamino) (methylthio) methylene) malononitrile Benzethonium Chloride Trenbolone Enanthate Prednisolone acetate Cisplatin Chlorodehydromethyl testosterone Ketoconazole 1,3-Di Iodo Benzene Methyl 2-oxo-2,3-dihydrobenzo[d]oxazole-7-carboxylate 3-Hydroxy-4-nitrobromobenzene 4-(2-Aminoethyl)-7-hydroxy-2H-chromoen-2-one 2-Ethyl-1,4-diaminobenzene 2-Ethylhexyl 4-aminobenzoate

Related products of tetrahydrofuran

CHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]COPPER(I)

Allylpalladium(II) Chloride Dimer

Chloro(1,5-cyclooctadiene)methylpalladium(II) 97%

XPhos Pd G1

RuPhos Pd G2

SPhos Pd G1, Methyl t-Butyl Ether Adduct

Chloro(1,5-cyclooctadiene)iridium(I) dimer

SPhos Pd G2