(Carbomethoxymethyl)triphenylphosphonium bromide
Synonym(s):(Carbomethoxymethyl)triphenylphosphonium bromide;NSC 136109
- CAS NO.：1779-58-4
- Empirical Formula: C21H20BrO2P
- Molecular Weight: 415.26
- MDL number: MFCD00011801
- EINECS: 217-222-0
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-05-27 17:25:41
What is (Carbomethoxymethyl)triphenylphosphonium bromide?
Chemical properties
white powder
The Uses of (Carbomethoxymethyl)triphenylphosphonium bromide
(Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction, substituted furanones for antifungal and cytostatic activities, photochromic dithienylethene derivatives, gem-diiodoalkanes containing allylic alcohols and highly substituted cyclopentenes and brazilanes via Au-catalyzed deoxygenative Nazarov cyclization. As reactant for asymmetric hydrogenation of α,β-unsaturated ester-phosphonates, studies of thermal decomposition of phosphonium alkyl ester salts.
What are the applications of Application
(Methoxycarbonylmethyl)triphenylphosphonium bromide is a reactant for the synthesis of GSK-3 inhibitors using the Wittig reaction
Purification Methods
Wash it with pet ether (b 40-50o), recrystallise it from CHCl3/Et2O and dry it at high vacuum at 65o. [Isler et al. Helv Chim Acta 40 1242 1957, Wittig & Haag Chem Ber 88 1654, 1664 1955, Beilstein 16 IV 981.]
Properties of (Carbomethoxymethyl)triphenylphosphonium bromide
| Melting point: | 165-170 °C (dec.) (lit.) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Soluble in methanol(almost transparency). |
| form | solid |
| color | White to Almost white |
| Sensitive | Hygroscopic |
| BRN | 3812975 |
| CAS DataBase Reference | 1779-58-4(CAS DataBase Reference) |
Safety information for (Carbomethoxymethyl)triphenylphosphonium bromide
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (Carbomethoxymethyl)triphenylphosphonium bromide
| InChIKey | VCWBQLMDSMSVRL-UHFFFAOYSA-M |
(Carbomethoxymethyl)triphenylphosphonium bromide manufacturer
Ina pharmaceuticals Pvt Ltd
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product: (2-Methoxy-2-oxoethyl) triphenyl phosphonium bromide 99%
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