3-Picoline-N-oxide
Synonym(s):3-Methylpyridine 1-oxide;3-Picoline N-oxide
- CAS NO.：1003-73-2
- Empirical Formula: C6H7NO
- Molecular Weight: 109.13
- MDL number: MFCD00006203
- EINECS: 213-714-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2025-01-27 09:38:02
What is 3-Picoline-N-oxide?
Chemical properties
PALE YELLOW TO BROWN CRYSTALLINE LOW MELTING MASS
The Uses of 3-Picoline-N-oxide
An intermediate in the preparation of nicotine derivatives.
Purification Methods
Purify the N-oxide by careful fractionation in vacuo. The distillate remains supercooled for several days before solidifying. It is a slightly hygroscopic solid which could melt in the hand. The picrate has m 149-151o (from EtOH). [Taylor & Corvetti Org Synth Coll Vol IV 654 1963, IR: Katritzky et al. J Chem Soc 3680 1959, Jaffé & Doak J Am Chem Soc 77 4441, 4481 1955, Boekelheide & Linn J Am Chem Soc 76 1286 1954]. [Beilstein 20 III/IV 2719, 20/5 V 517.]
Properties of 3-Picoline-N-oxide
| Melting point: | 37-39 °C(lit.) |
| Boiling point: | 150 °C15 mm Hg(lit.) |
| Density | 1.13 |
| refractive index | 1.5444 (estimate) |
| Flash point: | >230 °F |
| storage temp. | Sealed in dry,Room Temperature |
| solubility | >2000g/l |
| pka | pK1:10.921(+1) (25°C) |
| form | Crystalline Low Melting Mass |
| color | Pale yellow to brown |
| Water Solubility | soluble |
| Sensitive | Hygroscopic |
| BRN | 106327 |
| CAS DataBase Reference | 1003-73-2(CAS DataBase Reference) |
| NIST Chemistry Reference | Pyridine, 3-methyl-, 1-oxide(1003-73-2) |
| EPA Substance Registry System | Pyridine, 3-methyl-, 1-oxide (1003-73-2) |
Safety information for 3-Picoline-N-oxide
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P337+P313:IF eye irritation persists: Get medical advice/attention. |
Computed Descriptors for 3-Picoline-N-oxide
3-Picoline-N-oxide manufacturer
Lorven Biologics Pvt Ltd
1Y
Phone:+91-8884110005
Whatsapp: +91-8884110005
product: 1003-73-2 3-methyl pyridine N-oxide 98%
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