2-Bromo-4-methylaniline
Synonym(s):2-Bromo-p-toluidine;4-Amino-3-bromotoluene
- CAS NO.：583-68-6
- Empirical Formula: C7H8BrN
- Molecular Weight: 186.05
- MDL number: MFCD00007635
- EINECS: 209-515-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-05-27 23:54:55
What is 2-Bromo-4-methylaniline?
Chemical properties
clear light yellow to brown liquid
The Uses of 2-Bromo-4-methylaniline
2-Bromo-4-methylaniline has been used in the synthesis of iminophosphoranes.
General Description
2-Bromo-4-methylaniline participates in palladium catalyzed selective amination of 3-bromoquinoline to yield 3-(2-bromo-4-methylphenylamino) quinoline. It reacts with ethyl and methyl imidazo[1,2-a]pyridine-2-carboxylates in the presence of Me3Al to form amide.
Properties of 2-Bromo-4-methylaniline
| Melting point: | 14-16 °C (lit.) |
| Boiling point: | 240 °C (lit.) |
| Density | 1.5 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | >230 °F |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | Chloroform (Slightly) |
| form | Oil |
| pka | 2.97±0.10(Predicted) |
| color | Dark Yellow to Dark Beige |
| Specific Gravity | 1.500 |
| Water Solubility | Insoluble in water. |
| BRN | 1931711 |
| Stability: | Air Sensitive |
| CAS DataBase Reference | 583-68-6(CAS DataBase Reference) |
| NIST Chemistry Reference | Benzenamine, 2-bromo-4-methyl-(583-68-6) |
| EPA Substance Registry System | Benzenamine, 2-bromo-4-methyl- (583-68-6) |
Safety information for 2-Bromo-4-methylaniline
| Signal word | Danger |
| Pictogram(s) |
 Skull and Crossbones Acute Toxicity GHS06 |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P311:Call a POISON CENTER or doctor/physician. P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. |
Computed Descriptors for 2-Bromo-4-methylaniline
| InChIKey | UVRRJILIXQAAFK-UHFFFAOYSA-N |
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