2-Benzylaminopyridine
- CAS NO.：6935-27-9
- Empirical Formula: C12H12N2
- Molecular Weight: 184.24
- MDL number: MFCD00006251
- EINECS: 230-060-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-01-13 11:16:31
What is 2-Benzylaminopyridine?
Chemical properties
white to off-white powder
The Uses of 2-Benzylaminopyridine
2-(Benzylamino)pyridine is used as a reactant in the amination of aryl chlorides, bromides, and triflates catalyzed by palladium complexes.
Synthesis Reference(s)
Organic Syntheses, Coll. Vol. 4, p. 91, 1963
The Journal of Organic Chemistry, 67, p. 4965, 2002 DOI: 10.1021/jo020057z
General Description
2-Benzylaminopyridine on reaction with BBr3 yields the corresponding amino or hydroxy substituted compounds. It forms 5- and 6-coordinated organometallic complexes of gallium(III) and indium(III).
Properties of 2-Benzylaminopyridine
| Melting point: | 95-97 °C (lit.) |
| Boiling point: | 116-131 °C/0.6 mmHg (lit.) |
| Density | 1.1160 (rough estimate) |
| refractive index | 1.6266 (estimate) |
| Flash point: | 182°C/12mm |
| storage temp. | Sealed in dry,2-8°C |
| form | powder to crystal |
| pka | 6.61±0.10(Predicted) |
| color | White to Light yellow to Light orange |
| BRN | 134309 |
| CAS DataBase Reference | 6935-27-9(CAS DataBase Reference) |
| EPA Substance Registry System | 2-Pyridinamine, N-(phenylmethyl)- (6935-27-9) |
Safety information for 2-Benzylaminopyridine
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 2-Benzylaminopyridine
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