(1S,4S,8S)-5-Benzyl-8-methoxy-1,8-dimethyl-2-(2'-methylpropyl)-bicyclo [2.2.2]octa-2,5-diene
Synonym(s):(1S,4S,8S) Carreira DOLEFIN Ligand;(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethyl-2-bicyclo[2.2.2]octa-2,5-diene;(1S,4S,8S)--5-Benzyl-8-methoxy-1,8-dimethyl-2-(2′-methylpropyl)-bicyclo[2.2.2]octa-2,5-diene
- CAS NO.：862499-50-1
- Empirical Formula: C22H30O
- Molecular Weight: 310.47
- MDL number: MFCD09265063
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-09-12 18:52:05
![(1S,4S,8S)-5-Benzyl-8-methoxy-1,8-dimethyl-2-(2'-methylpropyl)-bicyclo [2.2.2]octa-2,5-diene Structural](https://img.chemicalbook.in/CAS/GIF/862499-50-1.gif)
What is (1S,4S,8S)-5-Benzyl-8-methoxy-1,8-dimethyl-2-(2'-methylpropyl)-bicyclo [2.2.2]octa-2,5-diene?
The Uses of (1S,4S,8S)-5-Benzyl-8-methoxy-1,8-dimethyl-2-(2'-methylpropyl)-bicyclo [2.2.2]octa-2,5-diene
General Description
(1S,4S,8S)-5-Benzyl-2-isobutyl-8-methoxy-1,8-dimethylbicyclo[2.2.2]octa-2,5-diene, an enantiopure diene ligand developed by Carreira, is most commonly used in asymmetric catalysis. It is generally prepared from commercially available (R)-carvone.
Properties of (1S,4S,8S)-5-Benzyl-8-methoxy-1,8-dimethyl-2-(2'-methylpropyl)-bicyclo [2.2.2]octa-2,5-diene
| Boiling point: | 392.1±42.0 °C(Predicted) |
| Density | 1.00±0.1 g/cm3(Predicted) |
| refractive index | n20/D1.522 |
| optical activity | [α]/D 84±5°, c = 0.5 in chloroform |
Safety information for (1S,4S,8S)-5-Benzyl-8-methoxy-1,8-dimethyl-2-(2'-methylpropyl)-bicyclo [2.2.2]octa-2,5-diene
Computed Descriptors for (1S,4S,8S)-5-Benzyl-8-methoxy-1,8-dimethyl-2-(2'-methylpropyl)-bicyclo [2.2.2]octa-2,5-diene
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