UiO-66-NH2(Zr)
- CAS NO.：1260119-00-3
- Empirical Formula: C48H30N6O32Zr6
- Molecular Weight: 1750.12
- Update Date: 2025-07-16 09:55:30
What is UiO-66-NH2(Zr)?
Definition
UiO-66-NH2(Zr), a zirconium-based functional metal–organic framework (MOF), was post synthetically modified via Schiff base reaction between aldehyde groups in glutaraldehyde and amino groups in UiO-66-NH2 and CO2-preabsorbed polyethyleneimine (PEI). Compared with pristine UiO-66-NH2, the PEIC@UiO adsorbents have reduced specific surface area (7–150 m2/g) but maintained the same crystal structure. Notably, the PEIC96@UiO adsorbent exhibited significantly improved CO2/N2 adsorption selectivity (48 vs 25) and higher CO2 adsorption capacity. The adsorbent also displayed moderate desorption energy (68 kJ/mol CO2), superior moisture endurance, and recyclability[1].
References
[1] Junjie Zhu. “Polyethyleneimine-Modified UiO-66-NH2(Zr) Metal–Organic Frameworks: Preparation and Enhanced CO2 Selective Adsorption.” ACS Omega 4 2 (2019): 3188–3197.
Properties of UiO-66-NH2(Zr)
| form | solid |
| color | Yellow |
| InChI | InChI=1S/6C8H7NO4.8O.6Zr/c6*9-6-3-4(7(10)11)1-2-5(6)8(12)13;;;;;;;;;;;;;;/h6*1-3H,9H2,(H,10,11)(H,12,13);;;;;;;;;;;;;;/q;;;;;;4*-2;4*-1;6*+4/p-12 |
Safety information for UiO-66-NH2(Zr)
Computed Descriptors for UiO-66-NH2(Zr)
| InChIKey | SGCQKKMGUIJGFK-UHFFFAOYSA-B |
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![Zirconium, tetra-μ3-hydroxytetra-μ3-oxohexakis[μ-[[1,1':4',1''-terphenyl]-4,4''-dicarboxylato(2-)-κO4:κO'4]]hexa-](https://img.chemicalbook.in/CAS/20210111/GIF/1072413-85-4.gif)
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