(S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
- CAS NO.:174467-31-3
- Empirical Formula: C52H48FeN2P2
- Molecular Weight: 818.76
- MDL number: MFCD04117705
- Update Date: 2023-04-23 13:52:06
What is (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene?
The Uses of (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
Chlorotricarbonyl(4,4'-di-t-butyl-2,2'-bipyridine)rhenium(I) is used for the reduction of carbon dioxide as a catalyst.
Reactions
- Ligand used for the palladium-catalyzed asymmetric coupling of potassium crotyltrifluoroborate with methyl 4-bromobenzoate.
- Ligand used for the gold-catalyzed phenol synthesis from furyldialkyne.
- Ligand for asymmetric palladium-catalyzed cross-coupling of aryl triflates with [( 6 -benzylamine)Cr(CO)3]
- Ligand used for the palladium-catalyzed asymmetric synthesis of α-allyl-α-aryl α-amino acids by tandem alkylation/π-allylation of α-iminoesters
Properties of (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
| alpha | -320.0° (c 1.0, CHCl3) |
| form | solid |
| color | orange-red |
| Stability: | store cold |
Safety information for (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
| Signal word | Warning |
| Pictogram(s) |
![]() Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for (S,S)-(-)-2,2'-Bis[(R)-(N,N-dimethylamino)(phenyl)methyl]-1,1'-bis(diphenylphosphino)ferrocene
New Products
Indole Methyl Resin tert-butyl 9-methoxy-3-azaspiro[5.5]undecane-3-carboxylate Boc-Arg-OH HCl H2O Boc-His(Boc)-OH 2-CTC Resin 4-Chloro-7-tosy1-7Hpyrrolo[2,3-d]pyrimidine 5,7-Dibromo-1H-indole 2,5-dichloro-N-hydroxy-4,6-dimethylpyridine-3-carboximidamide 2,2-Dimethoxy-7-azaspiro[3.5]nonane hydrochloride 4-chloromethyl-5-methyl-1,3-dioxol-2-one (DMDO-Cl) 1-Boc-4-cyanopiperidine R-2-BENZYLOXY PROPIONIC ACID 1,1’-CARBONYLDIIMIDAZOLE 1,1’-CARBONYLDI (1,2-4 TRIAZOLE) N-METHYL INDAZOLE-3-CARBOXYLIC ACID TETRAHYDRO-2H-PYRAN-3-OL 3-Pyridineacrylic acid tert-Butyl carbazate 2-Methoxyphenothiazine N-methyl -4-piperidone 2-((4-morpholinophenylamino) (methylthio) methylene) malononitrile 3-(4-morpholinophenylamino)-5-amino-1H-pyrazole-4-carbonitrile 2,4-dihydroxybenzaldehyde 1,3-Diethyl-1,3-DiphenylureaRelated products of tetrahydrofuran
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