R-(+)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bi-1,4-benzodioxin
- CAS NO.:503538-68-9
- Empirical Formula: C40H32O4P2
- Molecular Weight: 638.63
- MDL number: MFCD05861608
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-09-12 18:53:48
What is R-(+)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bi-1,4-benzodioxin?
Chemical properties
White crystalline powder
Reactions
- A chiral diphosphine ligand used in the highly-enantioselective hydrogenation of ketoesters, hydroxyketones, ketophosphonates and succinates.
- A ligand used for the dynamic kinetic resolution of α,β−unsaturated lactones via asymmetric copper-catalyzed conjugate reduction.
- Used in the intramolecular Heck reaction for the synthesis of diterpenoids.
- Used in asymmetric Pauson-Khand reaction.
- Used in asymmetric iminonitroso Diels-Alder reaction.
- Palladium catalyzed asymmetric hydrogenation of N-tosyl ketimines
Properties of R-(+)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bi-1,4-benzodioxin
| Melting point: | >260 °C |
| Boiling point: | 738.4±60.0 °C(Predicted) |
| storage temp. | Inert atmosphere,Room Temperature |
| form | Powder |
| color | white |
Safety information for R-(+)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bi-1,4-benzodioxin
Computed Descriptors for R-(+)-6,6'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-5,5'-bi-1,4-benzodioxin
New Products
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