(PHENYLTHIOMETHYL)TRIMETHYLSILANE
Synonym(s):(Phenylthiomethyl)trimethylsilane;(Trimethylsilyl)methyl phenyl sulfide;Phenyl (trimethylsilyl)methyl sulfide
- CAS NO.：17873-08-4
- Empirical Formula: C10H16SSi
- Molecular Weight: 196.38
- MDL number: MFCD00009838
- SAFETY DATA SHEET (SDS)
- Update Date: 2025-01-27 09:38:02
What is (PHENYLTHIOMETHYL)TRIMETHYLSILANE?
Physical properties
bp 158–159 °C/52 mmHg; d20 0.967 g cm?3; n20 D 1.5390.
The Uses of (PHENYLTHIOMETHYL)TRIMETHYLSILANE
lithio derivative is a one-carbon homologating agent leading to aldehydes via sila-Pummerer rearrangement, vinyl sulfides via Peterson alkenation, and vinylsilanes from silyl epoxides.
Purification Methods
If the sample is suspect, then add H2O, wash it with 10% aqueous NaOH, H2O again, dry (anhydrous CaCl2) and fractionally distil it through a 2ft column packed with glass helices. [Cooper J Am Chem Soc 76 3713 1954.]
Properties of (PHENYLTHIOMETHYL)TRIMETHYLSILANE
| Boiling point: | 158-159 °C52 mm Hg(lit.) |
| Density | 0.967 g/mL at 25 °C(lit.) |
| refractive index | n |
| Flash point: | 103 °F |
| solubility | sol most common organic solvents. |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Specific Gravity | 0.97 |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| BRN | 1932375 |
| NIST Chemistry Reference | Silane, trimethyl[(phenylthio)methyl]-(17873-08-4) |
Safety information for (PHENYLTHIOMETHYL)TRIMETHYLSILANE
| Signal word | Warning |
| Pictogram(s) |
 Flame Flammables GHS02  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H226:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P241:Use explosion-proof electrical/ventilating/lighting/…/equipment. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P337+P313:IF eye irritation persists: Get medical advice/attention. P370+P378:In case of fire: Use … for extinction. P403+P235:Store in a well-ventilated place. Keep cool. |
Computed Descriptors for (PHENYLTHIOMETHYL)TRIMETHYLSILANE
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