PHENYL AZIDE
Synonym(s):Phenyl azide solution
- CAS NO.:622-37-7
- Empirical Formula: C6H5N3
- Molecular Weight: 119.12
- MDL number: MFCD00040895
- EINECS: 210-730-3
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-01-13 11:24:58
What is PHENYL AZIDE?
The Uses of PHENYL AZIDE
Phenylazide in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).
2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry
Synthesis Reference(s)
Journal of the American Chemical Society, 89, p. 5284, 1967 DOI: 10.1021/ja00996a036
Tetrahedron Letters, 27, p. 4749, 1986 DOI: 10.1016/S0040-4039(00)85055-8
General Description
Azidobenzene solution can undergo click reaction with alkyne-functionalized oligomers to form O-ester-functionalized o-phenylenes, a group of aromatic foldamers with a good folding tendency in most solvents.
Safety Profile
Explodes when heated.Explosive or violent reactions with Lewis acids [e.g., aluminum chloride (explosive); sulfuric acid (violent)]. When heated to decomposition it emits toxic fumes of NOx.
Properties of PHENYL AZIDE
| Melting point: | -27.5°C |
| Boiling point: | 212.39°C (rough estimate) |
| Density | 1.0860 |
| vapor density | 73.5 at 22-24 mm |
| refractive index | 1.5589 |
| Flash point: | -12°C |
| storage temp. | -20°C |
| color | Pale-yellow oil |
| BRN | 742248 |
Safety information for PHENYL AZIDE
| Signal word | Danger |
| Pictogram(s) |
![]() Flame Flammables GHS02 ![]() Corrosion Corrosives GHS05 ![]() Exclamation Mark Irritant GHS07 ![]() Health Hazard GHS08 |
| GHS Hazard Statements |
H225:Flammable liquids H302:Acute toxicity,oral H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H373:Specific target organ toxicity, repeated exposure |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P280:Wear protective gloves/protective clothing/eye protection/face protection. P314:Get medical advice/attention if you feel unwell. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for PHENYL AZIDE
PHENYL AZIDE manufacturer
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