Mordant Black 3
Synonym(s):2-Hydroxy-1-(1-hydroxy-2-naphthylazo)-naphthalene-4-sulfonic acid sodium salt;Eriochrome blue-black B (C.I. 14640)
- CAS NO.：3564-14-5
- Empirical Formula: C20H15N2NaO5S
- Molecular Weight: 418.4
- MDL number: MFCD00003934
- EINECS: 222-639-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-04-24 14:57:00
What is Mordant Black 3?
Chemical properties
black fine crystalline powder
The Uses of Mordant Black 3
Eriochrome is to do titration indicator. Dubbed in aqueous solution or alcohol-soluble when used for the determination of calcium, magnesium, manganese, zinc and other metal ions, measured water hardness.
Preparation
4-Amino-3-hydroxynaphthalene-1-sulfonic acid diazotization, and Naphthalen-1-ol coupling.
Properties and Applications
blue light grey to blue black. Soluble in water is purple, soluble in ethanol (in red), Acetone, insoluble in Toluene. In concentrated sulfuric acid for skipper, after dilution for shallow sauce red; In concentrated nitric acid for yellow solution. Dye aqueous solution to join concentrated hydrochloric acid for pale red light brown; Join concentrated sodium hydroxide solution for red wine.
| Standard | Ironing Fastness | Light Fastness | Fulling | Persperation Fastness | Soaping | Water | |
| Alkali | Acid | ||||||
| ISO | 4-5 | 6 | 4-5 | 4 | 5 | 5 | 5 |
| AATCC | 4 | 6 | 4-5 | 5 | 5 | 5 | |
Purification Methods
Free it from metallic impurities by three precipitations from aqueous solution by addition of HCl. The precipitated dye is dried at 60o under vacuum and converted into the Na salt with the calculated amount of alkali. It is an indicator in the complexometry of Al, Fe and Zr. [Beilstein 16 III 319.]
Properties of Mordant Black 3
| storage temp. | Store at +15°C to +25°C. |
| solubility | 20g/l |
| form | Powder |
| Colour Index | 14640 |
| color | Purple to dark brown |
| PH | 9.5 (10g/l, H2O, 20℃) |
| Water Solubility | Soluble in water(20 g/L (20 C). |
| EPA Substance Registry System | C.I. Mordant Black 3 monosodium salt (3564-14-5) |
Safety information for Mordant Black 3
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H319:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P337+P313:IF eye irritation persists: Get medical advice/attention. |
Computed Descriptors for Mordant Black 3
Mordant Black 3 manufacturer
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