L(-)-10-Camphorsulfonyl chloride
Synonym(s):(−)-Camphor-10-sulfonyl chloride;(1R)-Camphor-10-sulfonic acid chloride
- CAS NO.：39262-22-1
- Empirical Formula: C10H15ClO3S
- Molecular Weight: 250.74
- MDL number: MFCD00064155
- EINECS: 628-057-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-04-24 14:59:15
What is L(-)-10-Camphorsulfonyl chloride?
Chemical properties
white to light yellow crystal powde
The Uses of L(-)-10-Camphorsulfonyl chloride
L(-)-10-Camphorsulfonyl chloride is a useful synthetic intermediate,it is used for asymmetric hydroxylation.
The Uses of L(-)-10-Camphorsulfonyl chloride
A chiral derivative of Camphor.
Purification Methods
If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]
Properties of L(-)-10-Camphorsulfonyl chloride
| Melting point: | 66-68 °C(lit.) |
| Boiling point: | 349.4±15.0 °C(Predicted) |
| alpha | -33 º (c=3, chloroform) |
| Density | 1.331±0.06 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Inert atmosphere,Room temperature |
| solubility | Acetone, Dichloromethane, Ethyl Acetate, Methanol |
| form | Solid |
| color | White |
| optical activity | [α]18/D 33°, c = 3 in chloroform |
| Water Solubility | Decomposes |
| Sensitive | Moisture Sensitive |
| BRN | 3205975 |
| CAS DataBase Reference | 39262-22-1(CAS DataBase Reference) |
Safety information for L(-)-10-Camphorsulfonyl chloride
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P363:Wash contaminated clothing before reuse. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for L(-)-10-Camphorsulfonyl chloride
| InChIKey | BGABKEVTHIJBIW-UHFFFAOYSA-N |
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