COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX
Synonym(s):Copper(I) triflate benzene complex;Cuprous trifluoromethanesulfonate benzene complex;Trifluoromethanesulfonic acid copper(I) salt benzene complex
- CAS NO.：42152-46-5
- Empirical Formula: C8H6Cu2F6O6S2
- Molecular Weight: 503.34
- MDL number: MFCD00043300
- EINECS: 255-686-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-05-27 23:34:46
What is COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX?
Chemical properties
Grey-greenish powder
The Uses of COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX
Copper(I) trifluoromethanesulfonate benzene complex can be used as a catalyst:
- To synthesize enol-esters via copper(I) carboxylate intermediate formation.
- In the enantioselective allylic oxidation of cyclic alkenes.
- To prepare 2,5-disubstituted pyrrolidine derivatives from N-alkenyl, alkynyl and alkyl N-benzoyloxysulfonamides via the sulfonamidyl radical formation.
It can also be used in combination with amino acid-based chiral phosphine ligands to catalyze asymmetric conjugate additions of alkylzincs to acyclic α,β-unsaturated ketones, affording β-alkylcarbonyls in high yield and with excellent enantioselectivity.
What are the applications of Application
Copper(I) trifluoromethanesulfonate benzene complex is catalyzes asymmetric conjugate additions
Properties of COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX
| Melting point: | 160 °C (dec.) (lit.) |
| Flash point: | 45 °F |
| storage temp. | Inert atmosphere,2-8°C |
| form | Powder |
| color | Gray-greenish |
| CAS DataBase Reference | 42152-46-5 |
Safety information for COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX
| Signal word | Warning |
| Pictogram(s) |
 Flame Flammables GHS02 |
| GHS Hazard Statements |
H228:Flammable solids |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P240:Ground/bond container and receiving equipment. P241:Use explosion-proof electrical/ventilating/lighting/…/equipment. P280:Wear protective gloves/protective clothing/eye protection/face protection. P370+P378:In case of fire: Use … for extinction. |
Computed Descriptors for COPPER(I) TRIFLUOROMETHANESULFONATE BENZENE COMPLEX
| InChIKey | OGHGYDFTMBZZJU-UHFFFAOYSA-M |
New Products
2-Bromo-4-hydroxypyridine 2-Benzyl-1,1,3,3-tetramethylisoindoline AMINO-O-TOLYL-ACETIC ACID AMINO(2-BROMOPHENYL)ACETIC ACID 6-BROMOTETRAZOLO[1,5-A]PYRIDINE 3-Oxocyclobutanecarboxylic acid 1,3-Diazaspiro[4.5]decane-2,4-dione, 8,8-difluoro- AMINO-(3-FLUORO-PHENYL)-ACETIC ACID Pyrrolo[1,2-a]pyrimidine-6-carboxylic acid, 4,6,7,8-tetrahydro-4-oxo-, sodium salt (1:1), (6S) Obidoxime hydrochloride API Piperazine, 1-(3-methoxyphenyl)-, hydrochloride (1:1) Decanoic acid, 2-[4-(phenylmethoxy)phenyl]ethyl ester 2,4-Dihydroxybenzaldehyde 3-Cyano-4-(2-methylpropoxy)benzenecarbothioamide 1-(2, 4-dichlorophenyl)-N-(2, 4-difluorophenyl)-N isopropyl-5-oxo-1H-1, 2, 4-trizole-4(5H)-carboxamide 2,4-Dihydroxyacetophenone 2-Chloro 5-Fluoro Pyridine Vasicinone 2-Chloroisonicotinic Acid Tween 80 or Polysorbate 80 2-Butyn-1-oL N-(4-fluoro-2-methoxy-5-nitrophenyl)-4-(1-methyl-1H-indol-3-yl)pyrimidin-2-amine Pirtobrutinib intd. N-(4-Cyano-3-(trifluoromethyl)phenyl)-2-methyloxirane-2-carboxamideRelated products of tetrahydrofuran
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