cis-3-hexene
- CAS NO.:7642-09-3
- Empirical Formula: C6H12
- Molecular Weight: 84.16
- MDL number: MFCD00085300
- SAFETY DATA SHEET (SDS)
- Update Date: 2025-01-27 09:38:02
What is cis-3-hexene?
Chemical properties
clear colorless to light yellow liquid
The Uses of cis-3-hexene
cis-3-Hexene is used as an organic chemical synthesis intermediate.
Definition
ChEBI: Cis-3-hexene is a 3-hexene in which the double bond adopts a cis-configuration. In this compound, there are two hydrogen atoms on one side and two ethyl groups on the other side of the double bond. The structures of cis-3-hexene and trans-3-hexene in gas phase were determined using electron diffraction and molecular mechanical calculations.
General Description
cis-3-Hexene is a symmetrical cis-disubstituted alkene that can be prepared by the hydroboration of 3-hexyne followed by protonolysis. The gas-phase study of its molecular structure by electron diffraction combined with molecular mechanical calculations reveals the presence of the (+ac, +ac) and the (-ac, +ac) forms. cis-3-Hexene undergoes epoxidation with dimethyldioxirane to form the corresponding epoxide.
Properties of cis-3-hexene
| Melting point: | -137.82°C |
| Boiling point: | 67 °C |
| Density | 0.677 |
| refractive index | 1.3935-1.3955 |
| Flash point: | -12 °C |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Specific Gravity | 0.677 |
| BRN | 1718858 |
| Dielectric constant | 2.1(24℃) |
| EPA Substance Registry System | 3-Hexene, (3Z)- (7642-09-3) |
Safety information for cis-3-hexene
| Signal word | Danger |
| Pictogram(s) |
![]() Flame Flammables GHS02 ![]() Exclamation Mark Irritant GHS07 ![]() Health Hazard GHS08 |
| GHS Hazard Statements |
H225:Flammable liquids H304:Aspiration hazard H319:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P331:Do NOT induce vomiting. P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for cis-3-hexene
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