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HomeProduct name listcis-3-hexene

cis-3-hexene

cis-3-hexene Structural

What is cis-3-hexene?

Chemical properties

clear colorless to light yellow liquid

The Uses of cis-3-hexene

cis-3-Hexene is used as an organic chemical synthesis intermediate.

Definition

ChEBI: Cis-3-hexene is a 3-hexene in which the double bond adopts a cis-configuration. In this compound, there are two hydrogen atoms on one side and two ethyl groups on the other side of the double bond. The structures of cis-3-hexene and trans-3-hexene in gas phase were determined using electron diffraction and molecular mechanical calculations.

General Description

cis-3-Hexene is a symmetrical cis-disubstituted alkene that can be prepared by the hydroboration of 3-hexyne followed by protonolysis. The gas-phase study of its molecular structure by electron diffraction combined with molecular mechanical calculations reveals the presence of the (+ac, +ac) and the (-ac, +ac) forms. cis-3-Hexene undergoes epoxidation with dimethyldioxirane to form the corresponding epoxide.

Properties of cis-3-hexene

Melting point: -137.82°C
Boiling point: 67 °C
Density  0.677
refractive index  1.3935-1.3955
Flash point: -12 °C
form  clear liquid
color  Colorless to Almost colorless
Specific Gravity 0.677
BRN  1718858
Dielectric constant 2.1(24℃)
EPA Substance Registry System 3-Hexene, (3Z)- (7642-09-3)

Safety information for cis-3-hexene

Signal word Danger
Pictogram(s)
ghs
Flame
Flammables
GHS02
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H225:Flammable liquids
H304:Aspiration hazard
H319:Serious eye damage/eye irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233:Keep container tightly closed.
P240:Ground/bond container and receiving equipment.
P331:Do NOT induce vomiting.
P301+P310:IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for cis-3-hexene

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