Acetylacetonatobis(2-phenylpyridine)iridium

Synonym(s):(ppy)₂Ir(acac);Bis[2-(2-pyridinyl-N)phenyl-C](acetylacetonato)iridium(III);Ir(ppy)₂(acac)

CAS NO.：337526-85-9
Empirical Formula: C27H23IrN2O2
Molecular Weight: 599.711
MDL number: MFCD12022553
EINECS: 803-559-6
SAFETY DATA SHEET (SDS)
Update Date: 2025-07-04 15:21:13

Acetylacetonatobis(2-phenylpyridine)iridium Structural

What is Acetylacetonatobis(2-phenylpyridine)iridium?

Description

Like?Ir(ppy)3, bis[2-(2-pyridinyl-N)phenyl-C](acetylacetonato)iridium(III), or?Ir(ppy)2(acac), is one of the most studied OLED materials due to its high quantum yields. When doped into 3,5-Diphenyl-4-(1-naphthyl)-1H-1,2,4-triazole (TAZ), very high external quantum efficiencies of (19.06 ± 1.0%) and luminous power efficiencies of 60±5 lm/W were achieved. This was attributed to the nearly 100% internal phosphorescence efficiency of Ir(ppy)2(acac), coupled with balanced hole and electron injection, and triplet exciton confinement within the light-emitting layer.

The Uses of Acetylacetonatobis(2-phenylpyridine)iridium

(ppy)₂Ir(acac) used in green phosphorescent OLED devices as dopant/emitter achieved high brightness of 130800 cd m_2 at a current density of 1550 mA cm_2 (13 V), and high quantum efficiency (15~16%).

Properties of Acetylacetonatobis(2-phenylpyridine)iridium

Melting point:	349-356°C
form	powder
color	Light yellow to Yellow to Orange
Absorption	λmax?259 in THF

Safety information for Acetylacetonatobis(2-phenylpyridine)iridium

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes	P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.