5-METHYL-2-HEPTEN-4-ONE
Synonym(s):Filbertone;Hazelnut ketone
- CAS NO.:81925-81-7
- Empirical Formula: C8H14O
- Molecular Weight: 126.2
- MDL number: MFCD00792509
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-04-03 14:17:14
What is 5-METHYL-2-HEPTEN-4-ONE?
Description
5-Methyl-2-hepten-4-one has a hazelnut, metallic, buttery odor and a hazelnut, buttery, mushroom taste.
Chemical properties
(2E)-5-Methyl-2-hepten-4-one has a fruity, hazelnut, and green odor reminding of dried
fruits and a characteristic, nutty, roasted, and nougat-like hazelnut flavor. It was
identified as the character compound of natural hazelnut flavor. Preparation is possible, for example, by Grignard reaction of 2-butyl magnesium chloride with
crotonaldehyde and subsequent oxidation or by reaction of 2-methylbutanoyl
chloride with propene.
The material is used in fragrances as top-note booster in exotic fruit and citrus
notes and in nut, cocoa, coffee, and so on, flavors.
Chemical properties
5-Methyl-2-hepten-4-one has a hazelnut, metallic, buttery odor and a hazelnut, buttery, mushroom taste.
Occurrence
Reported found in roasted hazelnuts and roasted filberts.
Aroma threshold values
Aroma characteristics at 1.0%: sweet roasted hazelnuts, rich nutty with a roasted nut skin.
Taste threshold values
Taste characteristics at 5 ppm: nutty, roasted, coffee, cocoa, brown with an earthy brown and meaty nuance, sugar fondant, delicate, hazelnut, with macadamia and pecan nuances
Trade name
Filbertone (Symrise).
Properties of 5-METHYL-2-HEPTEN-4-ONE
| Melting point: | -66.9°C (estimate) |
| Boiling point: | 170 °C(lit.) |
| Density | 0.845 g/mL at 25 °C(lit.) |
| FEMA | 3761 | 5-METHYL-2-HEPTEN-4-ONE |
| refractive index | n |
| Flash point: | 126 °F |
| Odor | at 1.00 % in dipropylene glycol. raw nut skin myrcene ketonic sweet hazelnut filbert |
| JECFA Number | 1133 |
| CAS DataBase Reference | 81925-81-7(CAS DataBase Reference) |
| EPA Substance Registry System | 2-Hepten-4-one, 5-methyl- (81925-81-7) |
Safety information for 5-METHYL-2-HEPTEN-4-ONE
| Signal word | Warning |
| Pictogram(s) |
![]() Flame Flammables GHS02 |
| GHS Hazard Statements |
H226:Flammable liquids |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. |
Computed Descriptors for 5-METHYL-2-HEPTEN-4-ONE
New Products
6-Methyl-2-(p-tolyl)imidazo[1,2-a]pyridine 4-FLUOROBENZOYLACETONITRILE (S)-Glycidyl Phthalimide Maleic hydrazide 8-Bromo-3-methyl xanthine 5-Chlorothiophene-2-carboxylic acid 4'-Hydroxyacetophenone 3-Bromophenylacetic acid Tridecanoic acid Pentadecanoic acid 3-AMINO-3-(2-FLUORO-PHENYL)-PROPIONIC ACID Hendecanoic acid 2,3-Dihydro-5,6-dimethoxy-2-(4-piperidinylmethyl)-1H-inden-1-one hydrochloride 4-pyridine methanol Ethyl 3,3- diethoxypropionate 5-Bromo-pyridine-2-carbaldehyde 1-Bromo-3-phenylpropane 4-(4-Methylpiperazino)aniline 2-Deoxy-2,2-difluoro-D-erythro-pentofuranose-3,5-dibenzoate-1-methanesulfonate N-((S)-1-(3-(3-amino-4-chloro-1-(2,2,2-trifluoroethyl)-1H-indazol-7-yl)-6-(3-methyl-3-(methylsulfonyl)but-1-yn-1-yl)pyridin-2-yl)-2-(3,5-difluorophenyl)ethyl)-2-((3bS,4aR)-5,5-difluoro-3-(trifluoromethyl)-3b,4,4a,5-tetrahydro-1H-cyclopropa[3,4]cyclopenta[1,2-c]pyrazol-1-yl)acetamide Methyl 2-(1-methyl-1H-pyrrol-2-yl)acetate 4-bromo-2-ethyl-3-fluorobenzoic acid 6-(chloromethyl)pteridine-2,4-diamine monohydrochloride 2-Chlorophenyl diphenyl chloromethaneRelated products of tetrahydrofuran








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