2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine
- CAS NO.:42573-57-9
- Empirical Formula: C14H9Cl6N3O
- Molecular Weight: 447.96
- MDL number: MFCD01940892
- EINECS: 255-893-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2025-08-05 18:30:54
What is 2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine?
The Uses of 2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine
Cationic photoinitiator. Nonionic photoacid generator.
What are the applications of Application
2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine is a cationic photoinitiator and nonionic photoacid generator
Properties and Applications
2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine (R–Cl) appears as a versatile high-performance photoinitiator (PI) under LED exposure at 385, 395, or 405 nm (intensities in the range ~9–140 mW cm?2). It can be used as an efficient Type I cleavable photoinitiator for free radical polymerization of (meth)acrylates upon LED (e.g., 405 nm) exposure. Its high FRP photoinitiation ability under air demonstrates its capability to reduce the oxygen inhibition effect. Moreover, the R–Cl/amine (or R–Cl/N-vinylcarbazole) two-component system exhibits a higher photoinitiation ability than R–Cl alone in some cases. R–Cl/Iod/NVK is also efficient for the cationic photopolymerization of epoxides, especially at 405 nm[1].
References
[1] Zhang, Jing et al. “A known photoinitiator for a novel technology: 2-(4-methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine for near UV or visible LED?.” Polymer Chemistry 20 (2014): 6019–6026.
Properties of 2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine
| Melting point: | 192-195 °C (lit.) |
| Boiling point: | 511.4±60.0 °C(Predicted) |
| Density | 1.605 |
| form | powder to crystal |
| pka | -1.88±0.10(Predicted) |
| color | Light yellow to Amber to Dark green |
| InChI | InChI=1S/C14H9Cl6N3O/c1-24-9-5-2-8(3-6-9)4-7-10-21-11(13(15,16)17)23-12(22-10)14(18,19)20/h2-7H,1H3 |
| EPA Substance Registry System | 1,3,5-Triazine, 2-[2-(4-methoxyphenyl)ethenyl]-4,6-bis(trichloromethyl)- (42573-57-9) |
Safety information for 2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine
| Signal word | Warning |
| Pictogram(s) |
![]() Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine
| InChIKey | MCNPOZMLKGDJGP-UHFFFAOYSA-N |
| SMILES | N1=C(C(Cl)(Cl)Cl)N=C(C(Cl)(Cl)Cl)N=C1C=CC1=CC=C(OC)C=C1 |
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