1,3-Bis(diphenylphosphino)propane
Synonym(s):dppp
- CAS NO.:6737-42-4
- Empirical Formula: C27H26P2
- Molecular Weight: 412.45
- MDL number: MFCD00003050
- EINECS: 229-791-2
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-10-21 13:02:29
What is 1,3-Bis(diphenylphosphino)propane?
Description
1,3-Bis(diphenylphosphino)propane (Dppp) is a bidentate ligand used typically in coordination chemistry and homogeneous catalysis. Common applications include palladium chemistry, but can also include reactions involving other transition metals such as nickel or rhodium.
The Uses of 1,3-Bis(diphenylphosphino)propane
1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.
Properties of 1,3-Bis(diphenylphosphino)propane
Melting point: | 63-65 °C (lit.) |
Boiling point: | 529.7±33.0 °C(Predicted) |
Flash point: | 235°C |
storage temp. | Inert atmosphere,Room Temperature |
appearance | White solid |
form | Granules or Powder |
color | White to light yellow-beige |
Water Solubility | insoluble |
Sensitive | Air Sensitive |
Safety information for 1,3-Bis(diphenylphosphino)propane
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 1,3-Bis(diphenylphosphino)propane
InChIKey | LVEYOSJUKRVCCF-UHFFFAOYSA-N |
Abamectin manufacturer
Vardhaman P Golechha
New Products
3-N-BOC-(S)-AMINO BUTYRONITRILE 4-Piperidinopiperidine 2-Methyl-4-nitrobenzoic acid 2-(4-bromophenyl)-2-methylpropanoic acid 4-Acetyl-2-methylbenzoicacid Acetyl-meldrum's acid Ethyl-4-Pyrazole carboxylate 2,6 Di acetylpyridine 2,6-Pyridinedimethanol 5,7-Dichloro-3H-Imidazo[4,5-B]Pyridine 5-Bromo-2-Methoxy-4-Methyl-3-Nitropyridine 2-Fluoro-5-Iodopyridine 2-Fluoro-5-Methylpyridine 2-Chloro-3-Bromo-5-Amiopyridine METHYL-4-(BUTYRYLAMINO)3-METHYL-5-NITROBENZOATE TRANS-CYCLOBUTANE-1,2- DICARBOXYLIC ACID 5-Nitro indazole R-(-)-5-(2-AMINO-PROPYL)-2-METHOXY-BENZENESULFONAMIDE 1,3-cyclohexanedione 4-Aminophenaethylalchol (S)-(+)-4-BENZYL-2-OXAZOLIDINONE 3-NITRO-5-ACETYL IMINODIBENZYL 4-FLUORO PHENYL MAGNESIUM BROMIDE 1.0 M IN THF 1-HYDROXY-4-METHYL6-(2,4,4-TRI METHYL PHENYL)-2-PYRIDONE MONO ETHANOL AMINE(PIROCTONE OLAMINE)Related products of tetrahydrofuran
You may like
-
6737-42-4 1,3-Bis(diphenylphosphino)propane 98%View Details
6737-42-4 -
6737-42-4 99%View Details
6737-42-4 -
2,3 Dichloro-4-Hydroxy Aniline 39183-17-0 99%View Details
39183-17-0 -
17673-56-2 99%View Details
17673-56-2 -
13463-67-7 Titanium Dioxide 99%View Details
13463-67-7 -
143-07-7 99%View Details
143-07-7 -
20776-67-4 99%View Details
20776-67-4 -
acid blue 113, acid navy blue , wool navy blue 0View Details
3351-05-1