[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)

Synonym(s):Ni(dppf)Cl₂

CAS NO.：67292-34-6
Empirical Formula: C34H22Cl2FeNiP2
Molecular Weight: 677.94
MDL number: MFCD00270284
SAFETY DATA SHEET (SDS)
Update Date: 2025-07-04 15:19:29

[1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) Structural

What is [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)?

Chemical properties

Yellow powder

The Uses of [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)

(1,1''-Bis(diphenylphosphino)ferrocene)dichloronickel(II) is an organometallic catalyst used in a variety of synthetic applications, such as the gem-?difluoropropargylation of alkylzinc reagents, or cross coupling reactions to form 2,?3,?5,?6-?tetrasubstituted dehydropiperidines.

The Uses of [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)

suzuki reaction

The Uses of [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)

diphosphine 1,1'-bis(diphenylphosphino)ferrocene (dppf) are used in transition metal-catalyzed reactions to synthesize pharmaceuticals and agrochemicals.

Properties of [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)

Melting point:	285 °C (dec.)(lit.)
storage temp.	Inert atmosphere,Room Temperature
form	crystal
color	green micro
Water Solubility	Insoluble in water.
Exposure limits	NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3

Safety information for [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II)

Signal word	Danger
Pictogram(s)	Health Hazard GHS08
GHS Hazard Statements	H317:Sensitisation, Skin H334:Sensitisation, respiratory H350:Carcinogenicity
Precautionary Statement Codes	P201:Obtain special instructions before use. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P308+P313:IF exposed or concerned: Get medical advice/attention.