1-Fluorododecane
Synonym(s):n-Dodecyl fluoride
- CAS NO.：334-68-9
- Empirical Formula: C12H25F
- Molecular Weight: 188.33
- MDL number: MFCD00013580
- EINECS: 206-381-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-09-12 18:53:29
What is 1-Fluorododecane?
Synthesis Reference(s)
Tetrahedron Letters, 28, p. 4733, 1987 DOI: 10.1016/S0040-4039(00)96612-7
General Description
1-Fluorododecane is a long chain 1-fluoroalkane. It can be synthesized from the reaction between 1-dodecanol, N,N-diethyl-α,α-difluoro-[3,5-bis(1H,1H,2H,2H-perfluorodecyl)benzyl]amine and heptane. 1-Fluorododecane undergoes reaction with dibromomethane and titanocene dichloride in the presence of triethyl aluminium (Et3Al) to afford a mixture of 1-chlorododecane and 1-bromododecane. 1-Fluorododecane can also be prepared from 1-hydroxydodecane.
Properties of 1-Fluorododecane
| Melting point: | -13°C |
| Boiling point: | 225-227°C |
| Density | 0.807 g/mL at 25 °C (lit.) |
| refractive index | n |
| Flash point: | 223 °F |
| Specific Gravity | 0.837 |
| CAS DataBase Reference | 334-68-9(CAS DataBase Reference) |
| EPA Substance Registry System | Dodecane, 1-fluoro- (334-68-9) |
Safety information for 1-Fluorododecane
| Signal word | Danger |
| Pictogram(s) |
 Skull and Crossbones Acute Toxicity GHS06 |
| GHS Hazard Statements |
H300:Acute toxicity,oral H413:Hazardous to the aquatic environment, long-term hazard |
| Precautionary Statement Codes |
P273:Avoid release to the environment. |
Computed Descriptors for 1-Fluorododecane
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