1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole
- CAS NO.：69352-04-1
- Empirical Formula: C9H10ClIO
- Molecular Weight: 296.53
- MDL number: MFCD21648251
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-05-28 03:31:47
What is 1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole?
The Uses of 1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole
1-?Chloro-?1,?3-?dihydro-?3,?3-?dimethyl-?1,?2-?benziodioxole is used as a reactant in one-pot preparation of hypervalent iodine(III)-CF3 reagent for the use in electrophilic trifluoromethylation reactions.
The Uses of 1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole
1-Chloro-3,3-dimethylbenziodoxole is a crystalline, air-stable, yellow chloroiodane compound which finds use as a starting material for production of other hypervalent iodine compounds. It can also be used as a mild chlorinating reagent. The compound shows good solubility in polar organic solvents, typically dichloromethane or ethyl acetate.
Properties of 1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole
| Melting point: | 143-145 °C(Solv: carbon tetrachloride (56-23-5)) |
Safety information for 1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole
| Signal word | Danger |
| Pictogram(s) |
 Flame Over Circle Oxidizers GHS03  Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H272:Oxidising liquids;Oxidising solids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 1-Chloro-1,3-dihydro-3,3-diMethyl-1,2-benziodoxole
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