Flammable liquids, Category 3
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 2
H226 Flammable liquid and vapour
H401 Toxic to aquatic life
H411 Toxic to aquatic life with long lasting effects
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 Keep container tightly closed.
P240 Ground and bond container and receiving equipment.
P241 Use explosion-proof [electrical/ventilating/lighting/...] equipment.
P242 Use non-sparking tools.
P243 Take action to prevent static discharges.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P273 Avoid release to the environment.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse affected areas with water [or shower].
P370+P378 In case of fire: Use ... to extinguish.
P391 Collect spillage.
P403+P235 Store in a well-ventilated place. Keep cool.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
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Fresh air, rest. Refer for medical attention.
Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Do NOT induce vomiting. Refer for medical attention .
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Use dry chemical, carbon dioxide or alcohol-resistant foam.
Flammable. Heating will cause rise in pressure with risk of bursting. Above 54°C explosive vapour/air mixtures may be formed.
Use powder, AFFF, foam, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.
Ventilation. Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
Prevent further spillage or leakage if it is safe to do so. Do not let the chemical enter drains. Discharge into the environment must be avoided.
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
NO open flames, NO sparks and NO smoking. Above 54°C use a closed system, ventilation and explosion-proof electrical equipment. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Fireproof. Separated from strong oxidants, strong acids, peroxides and aluminium chloride. Store only if stabilized.
TLV: 50 ppm as TWA; 100 ppm as STEL; A4 (not classifiable as a human carcinogen).MAK: 98 mg/m3, 20 ppm; peak limitation category: I(2); pregnancy risk group: D
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Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear face shield or eye protection in combination with breathing protection.
Protective gloves. Protective clothing.
Use ventilation, local exhaust or breathing protection.
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colourless liquid with a strong and unpleasant odour
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-77°C(lit.)
168°C(lit.)
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52°C
489-515°C
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3.58
7.03E-05mmHg at 25°C
0.893g/mLat 25°C(lit.)
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Vapours are uninhibited and may polymerize, causing blockage of vents.The substance if not stabilized will polymerize with generation of heat. Decomposes on heating. This produces toxic fumes and gases. The substance is a strong reducing agent. It reacts violently with oxidants. Reacts violently with aluminium salts.
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The substance is irritating to the eyes, skin and respiratory tract. The substance may cause effects on the nervous system.
Repeated or prolonged contact with skin may cause dermatitis. The substance may have effects on the liver. This may result in fatty degeneration.
A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C.
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The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN2618 (For reference only, please check.)
IMDG: UN2618 (For reference only, please check.)
IATA: UN2618 (For reference only, please check.)
ADR/RID: VINYLTOLUENES, STABILIZED (For reference only, please check.)
IMDG: VINYLTOLUENES, STABILIZED (For reference only, please check.)
IATA: VINYLTOLUENES, STABILIZED (For reference only, please check.)
ADR/RID: 3 (For reference only, please check.)
IMDG: 3 (For reference only, please check.)
IATA: 3 (For reference only, please check.)
ADR/RID: III (For reference only, please check.)
IMDG: III (For reference only, please check.)
IATA: III (For reference only, please check.)
ADR/RID: Yes
IMDG: Yes
IATA: Yes
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The information on this card applies to a mixture of m- and p-isomers.Use of alcoholic beverages enhances the harmful effect.An added stabilizer or inhibitor can influence the toxicological properties of this substance, consult an expert.