Hydrogen SDS
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifier
- Product name： Hydrogen
- CAS： 1333-74-0
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses： For R&D use only. Not for medicinal, household or other use.
- Uses advised against： none
Company Identification
- Company：Chemicalbook.in
- Address：5 vasavi Layout Basaveswara Nilayam Pragathi Nagar Hyderabad, India -500090
- Telephone：+91 9550333722
SECTION 2: Hazards identification
Classification of the substance or mixture
Gases under pressure: Compressed gas
Flammable gases, Category 1A, Flammable gas
GHS label elements, including precautionary statements
-
Pictogram(s)
- Signal word Danger
H220 Extremely flammable gas
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P377 Leaking gas fire: Do not extinguish, unless leak can be stopped safely.
P381 In case of leakage, eliminate all ignition sources.
P410+P403 Protect from sunlight. Store in a well-ventilated place.
P403 Store in a well-ventilated place.
none
Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
Substance
- Chemical name: Hydrogen
- Common names and synonyms: Hydrogen
- CAS number: 1333-74-0
- EC number: 215-605-7
- Concentration: 100%
SECTION 4: First aid measures
Description of necessary first-aid measures
Fresh air, rest.
ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer immediately for medical attention.
ON FROSTBITE: rinse with plenty of water. Refer immediately for medical attention.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms/effects, acute and delayed
Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]: Vapors may cause dizziness or asphyxiation without warning. Some may be irritating if inhaled at high concentrations. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating and/or toxic gases. (ERG, 2016)
Indication of immediate medical attention and special treatment needed, if necessary
no data available
SECTION 5: Firefighting measures
Suitable extinguishing media
Approach fire with caution as high-temperature flame is practically invisible. Stop flow of gas before extinguishing fire. Use water spray to keep fire-exposed containers cool. Use flooding quantities of water as fog or spray.
Specific hazards arising from the chemical
Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]: EXTREMELY FLAMMABLE. Will be easily ignited by heat, sparks or flames. Will form explosive mixtures with air. Vapors from liquefied gas are initially heavier than air and spread along ground. CAUTION: Hydrogen (UN1049), Deuterium (UN1957), Hydrogen, refrigerated liquid (UN1966) and Methane (UN1971) are lighter than air and will rise. Hydrogen and Deuterium fires are difficult to detect since they burn with an invisible flame. Use an alternate method of detection (thermal camera, broom handle, etc.) Vapors may travel to source of ignition and flash back. Cylinders exposed to fire may vent and release flammable gas through pressure relief devices. Containers may explode when heated. Ruptured cylinders may rocket. (ERG, 2016)
Special protective actions for fire-fighters
Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with water spray, powder, carbon dioxide. In case of fire: keep cylinder cool by spraying with water. Combat fire from a sheltered position.
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Evacuate danger area! Consult an expert! Ventilation. Remove all ignition sources. Remove vapour with fine water spray.
Environmental precautions
Evacuate danger area! Consult an expert! Ventilation. Remove all ignition sources. Remove vapour with fine water spray.
Methods and materials for containment and cleaning up
Eliminate all ignition sources. Approach release from upwind. Stop or control the leak, if this can be done without undue risk. Use water spray to disperse vapors and protect personnel.
SECTION 7: Handling and storage
Precautions for safe handling
NO open flames, NO sparks and NO smoking. Closed system, ventilation, explosion-proof electrical equipment and lighting. Use non-sparking handtools. Do not handle cylinders with oily hands. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Conditions for safe storage, including any incompatibilities
Fireproof. Cool. Ventilation along the floor and ceiling. Separated from oxidizing materials.Store in a cool, dry, well-ventilated location. Outside or detached storage is preferred. Isolate from oxygen, halogens, other oxidizing materials.
SECTION 8: Exposure controls/personal protection
Control parameters
| Component | Hydrogen | |||
|---|---|---|---|---|
| CAS No. | 1333-74-0 | |||
| Limit value - Eight hours | Limit value - Short term | |||
| ppm | mg/m3 | ppm | mg/m3 | |
| Canada - Ontario | (1) | ? | ? | ? |
| New Zealand | (1) | ? | ? | ? |
| Remarks | ||||
| Canada - Ontario | (1) Simple asphyxiant | |||
| New Zealand | (1) Simple asphyxiant - may present an explosion hazard | |||
no data available
Appropriate engineering controls
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Individual protection measures, such as personal protective equipment (PPE)
Wear face shield.
Cold-insulating gloves.
Use ventilation.
no data available
SECTION 9: Physical and chemical properties and safety characteristics
-
Physical state：
Hydrogen is a colorless, odorless gas. It is easily ignited. Once ignited it burns with a pale blue, almost invisible flame. The vapors are lighter than air. It is flammable over a wide range of vapor/air concentrations. Hydrogen is not toxic but is a simple asphyxiate by the displacement of oxygen in the air. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket. Hydrogen is used to make other chemicals and in oxyhydrogen welding and cutting.
-
Colour：
Colorless gas
-
Odour：
Odorless
-
Melting point/freezing point：
-259°C
-
Boiling point or initial boiling point and boiling range：
?252.8°C(lit.)
-
Flammability：
Extremely flammable. Many reactions may cause fire or explosion.
-
Lower and upper explosion limit/flammability limit：
LOWER: 4.0%; UPPER: 75% (% BY VOL)
-
Flash point：
<-150°C
-
Auto-ignition temperature：
1060°F
-
Decomposition temperature：
no data available
-
pH：
no data available
-
Kinematic viscosity：
no data available
-
Solubility：
1.62 mg/L at 21 deg C
-
Partition coefficient n-octanol/water：
no data available
-
Vapour pressure：
1.24X10+6 mm Hg at 25 deg C
-
Density and/or relative density：
0.0899
-
Relative vapour density：
0.07 (21 °C, vs air)
-
Particle characteristics：
no data available
SECTION 10: Stability and reactivity
Reactivity
Heating may cause violent combustion or explosion. Reacts violently with halogens, oxidizing materials and greases. This generates fire and explosion hazard. Metal catalysts, such as platinum and nickel, greatly enhance these reactions.
Chemical stability
no data available
Possibility of hazardous reactions
HIGHLY DANGEROUS WHEN EXPOSED TO HEAT, FLAME ...The gas mixes well with air, explosive mixtures are easily formed. The gas is lighter than air.Finely divided platinum and some other metals will cause a mixture of hydrogen and oxygen to explode at ordinary temperatures. If a jet of hydrogen in air impinges on platinum black the metal surface gets hot enough to ignite the gases, [Mellor 1:325(1946-1947)]. Explosive reactions occur upon ignition of mixtures of nitrogen trifluoride with good reducing agents such as ammonia, hydrogen, hydrogen sulfide or methane. Mixtures of hydrogen, carbon monoxide, or methane and oxygen difluoride are exploded when a spark is discharged, [Mellor 2, Supp. 1:192(1956)]. An explosion occurred upon heating 1'-pentol and 1''-pentol under hydrogen pressure. It appears that this acetylenic compound under certain conditions suddenly breaks down to form elemental carbon, hydrogen, and carbon monoxide with the release of sufficient energy to develop pressures in excess of 1000 atmospheres, [AIChE Loss Prevention, p1, (1967)].
Conditions to avoid
no data available
Incompatible materials
Release of hydrogen @ 47.5 bar into a vented 17.5-l chromium-plated sphere caused explosive ignition. Hydrogen
Hazardous decomposition products
no data available
SECTION 11: Toxicological information
Acute toxicity
- Oral: no data available
- Inhalation: no data available
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
Asphyxiation. See Notes. Exposure to cold gas could cause frostbite.
STOT-repeated exposure
no data available
Aspiration hazard
On loss of containment this substance can cause suffocation by lowering the oxygen content of the air in confined areas.
SECTION 12: Ecological information
Toxicity
- Toxicity to fish: no data available
- Toxicity to daphnia and other aquatic invertebrates: no data available
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Other adverse effects
no data available
SECTION 13: Disposal considerations
Disposal methods
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
UN Number
ADR/RID: UN3468 (For reference only, please check.)
IMDG: UN3468 (For reference only, please check.)
IATA: UN3468 (For reference only, please check.)
UN Proper Shipping Name
ADR/RID: HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM CONTAINED IN EQUIPMENT or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM PACKED WITH EQUIPMENT (For reference only, please check.)
IMDG: HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM CONTAINED IN EQUIPMENT or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM PACKED WITH EQUIPMENT (For reference only, please check.)
IATA: HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM CONTAINED IN EQUIPMENT or HYDROGEN IN A METAL HYDRIDE STORAGE SYSTEM PACKED WITH EQUIPMENT (For reference only, please check.)
Transport hazard class(es)
ADR/RID: 2.1 (For reference only, please check.)
IMDG: 2.1 (For reference only, please check.)
IATA: 2.1 (For reference only, please check.)
Packing group, if applicable
ADR/RID: (For reference only, please check.)
IMDG: (For reference only, please check.)
IATA: (For reference only, please check.)
Environmental hazards
ADR/RID: No
IMDG: No
IATA: No
Special precautions for user
no data available
Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
Safety, health and environmental regulations specific for the product in question
SECTION 16: Other information
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/
Other Information
High concentrations in the air cause a deficiency of oxygen with the risk of unconsciousness or death.Check oxygen content before entering the area.Measure hydrogen concentrations with suitable gas detector (a normal flammable gas detector is NOT suitable for the purpose).