Di-''isononyl'' phthalate SDS
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifier
- Product name： Di-''isononyl'' phthalate
- CAS： 28553-12-0
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses： For R&D use only. Not for medicinal, household or other use.
- Uses advised against： none
Company Identification
- Company：Chemicalbook.in
- Address：5 vasavi Layout Basaveswara Nilayam Pragathi Nagar Hyderabad, India -500090
- Telephone：+91 9550333722
SECTION 2: Hazards identification
Classification of the substance or mixture
Not classified.
GHS label elements, including precautionary statements
- Signal word No signal word
none
none
none
none
none
Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
Substance
- Chemical name: Di-''isononyl'' phthalate
- Common names and synonyms: Di-''isononyl'' phthalate
- CAS number: 28553-12-0
- EC number: 249-079-5
- Concentration: 100%
SECTION 4: First aid measures
Description of necessary first-aid measures
Move the victim into fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration and consult a doctor immediately. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical.
Rinse and then wash skin with water and soap.
Rinse with plenty of water for several minutes (remove contact lenses if easily possible).
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms/effects, acute and delayed
Produces no ill effects at normal temperatures, but may give off irritating vapors at high temperatures. (USCG, 1999)
Indication of immediate medical attention and special treatment needed, if necessary
Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. Esters and related compounds
SECTION 5: Firefighting measures
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus for firefighting if necessary.
Specific hazards arising from the chemical
This chemical is combustible. (NTP, 1992)
Special protective actions for fire-fighters
Use water spray, powder, alcohol-resistant foam, carbon dioxide.
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Collect leaking and spilled liquid in covered containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
Environmental precautions
Collect leaking and spilled liquid in covered containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
Methods and materials for containment and cleaning up
ACCIDENTAL RELEASE MEASURES: Personal precautions, protective equipment and emergency procedures: Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Environmental precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Methods and materials for containment and cleaning up: Soak up with inert absorbent material and dispose of as hazardous waste. Keep in suitable, closed containers for disposal.
SECTION 7: Handling and storage
Precautions for safe handling
NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Storage class (TRGS 510): Non Combustible Liquids.
SECTION 8: Exposure controls/personal protection
Control parameters
| Component | Di-''isononyl'' phthalate | |||
|---|---|---|---|---|
| CAS No. | 28553-12-0 | |||
| Limit value - Eight hours | Limit value - Short term | |||
| ppm | mg/m3 | ppm | mg/m3 | |
| Denmark | ? | 3 | ? | 6 |
| Ireland | ? | 5 | ? | ? |
| New Zealand | ? | 5 | ? | ? |
| United Kingdom | ? | 5 | ? | ? |
| Remarks | ||||
no data available
Appropriate engineering controls
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Individual protection measures, such as personal protective equipment (PPE)
Wear safety spectacles.
Protective gloves.
Use ventilation.
no data available
SECTION 9: Physical and chemical properties and safety characteristics
-
Physical state：
Di-isononyl phthalate is an oily colorless liquid with a slight ester odor. Denser than water. Insoluble in water. (USCG, 1999)
-
Colour：
Colorless liquid
-
Odour：
no data available
-
Melting point/freezing point：
-43 °C
-
Boiling point or initial boiling point and boiling range：
244-252 °C (5 mmHg)
-
Flammability：
Combustible.
-
Lower and upper explosion limit/flammability limit：
no data available
-
Flash point：
235°C
-
Auto-ignition temperature：
380°C
-
Decomposition temperature：
no data available
-
pH：
no data available
-
Kinematic viscosity：
500 cST at 0 deg C; 102 cST at 20 deg C; 37 cSt at 37.8 deg C; 6 cSt at 100 deg C
-
Solubility：
Insoluble (<1 mg/ml at 70° F) (NTP, 1992)
-
Partition coefficient n-octanol/water：
log Kow = 9.37 (est)
-
Vapour pressure：
5.4X10-7 mm Hg at 25 deg C
-
Density and/or relative density：
0.972g/mLat 25°C(lit.)
-
Relative vapour density：
no data available
-
Particle characteristics：
no data available
SECTION 10: Stability and reactivity
Reactivity
no data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
DI-ISONONYL PHTHALATE reacts exothermically with acids to generate isononyl alcohol and phthalic acid. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by interaction with caustic solutions. Flammable hydrogen is generated by mixing with alkali metals and hydrides. Can generate electrostatic charges. [Handling Chemicals Safely, 1980. p. 250].
Conditions to avoid
no data available
Incompatible materials
no data available
Hazardous decomposition products
When heated to decomposition it emits acrid smoke and irritating vapors.
SECTION 11: Toxicological information
Acute toxicity
- Oral: LD50 Rat oral >10 g/kg
- Inhalation: LC50 Rat inhalation >4.4 mg/L for 4hr
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
no data available
STOT-repeated exposure
Tumours have been detected in experimental animals but may not be relevant to humans.
Aspiration hazard
Evaporation at 20°C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.
SECTION 12: Ecological information
Toxicity
- Toxicity to fish: LC50; Species: Pimephales promelas (Fathead minnow); Conditions: flow through, 20-24 deg C, pH 6.6-7.2; Concentration: >0.19 mg/L for 96 hr
- Toxicity to daphnia and other aquatic invertebrates: no data available
- Toxicity to algae: EC50; Species: Pseudokirchneriella subcapitata (Green algae) 2-3 instar; Conditions: freshwater, static, 22-24 deg C, pH 7.6-7.9, hardness 25-50 mg/L CaCO3, alkalinity 25-50 mg/L CaCO3; Concentration: 1800 ug/L for 96 hr; Effect: decreased population abundance /> or = 95% purity
- Toxicity to microorganisms: no data available
Persistence and degradability
AEROBIC: A shake flask CO2 evolution test using an inoculum prepared from soil and sewage, resulted in 99% biodegradation of diisononyl phthalate and 62% theoretical CO2 evolution after a 28 day incubation period(1). Diisononyl phthalate had a biodegradation half-life of 5.31 days with a 7.1 day lag time(1). Diisononyl phthalate was classified as slowly degradable in semi-continuous activated sludge test in which 32% degradation was achieved for a 3 ppm feed(2). In another semi-continuous activated sludge test (Soap and Detergent Association procedure), the mean percentage degradation for diisononyl phthalate (3 ppm) was 67.8% in 24 hr(2). In a die-away phase of the testing, it took 5 days to achieve 90% degradation(2). Using a modified Sturm test, diisononyl phthalate was biodegraded an average of 79% in 28 days(3). Diisononyl had degradation rates of 68 and >90% at initial concentrations of 1-3 and 3 ppm, in 1 and 4 days incubation time, respectively, using an activated sludge inoculum(4). Diisononyl phthalate exhibited a primary biodegradation to intermediates of >95% in 12 days from a starting concentration of 1 ppm using a fresh water inoculum(4). Ultimate biodegradation in fresh water sediment was <1 to 8% in 28 days with respective starting concentrations of 10 to 0.02 ppm(5). Total degradation of diisononyl phthalate with starting concentrations of 45, 35, and 100 ppm using activated sludge inoculum with a 28 day incubation period were 70, 57, and 71%, respectively(4). Diisononyl phthalate, present at 100 mg/L, reached 74% of its theoretical BOD in 4 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test(6).
Bioaccumulative potential
An estimated BCF of 230 was calculated in fish for diisononyl phthalate(SRC), using an estimated log Kow of 9.37(1) and a regression-derived equation(1). According to a classification scheme(2), this BCF suggests the potential for bioconcentration in aquatic organisms is high(SRC). However, bioconcentration studies on compounds which are structurally similar suggest that bioconcentration may be lower than that indicated by the regression-derived equations due to the ability of aquatic organisms to readily metabolize this class of compounds(3).
Mobility in soil
Using a structure estimation method based on molecular connectivity indices(1), the log Koc of diisononyl phthalate can be estimated to be 5.52(SRC). Another estimated value is reported as 5.49(2). According to a classification scheme(3), these estimated Koc values suggest that diisononyl phthalate is expected to be immobile in soil.
Other adverse effects
no data available
SECTION 13: Disposal considerations
Disposal methods
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
UN Number
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
UN Proper Shipping Name
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
Transport hazard class(es)
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
Packing group, if applicable
ADR/RID: Not dangerous goods. (For reference only, please check.)
IMDG: Not dangerous goods. (For reference only, please check.)
IATA: Not dangerous goods. (For reference only, please check.)
Environmental hazards
ADR/RID: No
IMDG: No
IATA: No
Special precautions for user
no data available
Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
Safety, health and environmental regulations specific for the product in question
SECTION 16: Other information
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/
Other Information
Other melting points: between -40°C and -46°C.The recommendations on this Card also apply to 1,2-Benzenecarboxylic acid, di-C8-10-branched alkyl esters, C9-rich (CAS 68515-48-0) (DINP 1 is a trade name).