Di-''isodecyl'' phthalate SDS
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifier
- Product name： Di-''isodecyl'' phthalate
- CAS： 26761-40-0
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses： For R&D use only. Not for medicinal, household or other use.
- Uses advised against： none
Company Identification
- Company：Chemicalbook.in
- Address：5 vasavi Layout Basaveswara Nilayam Pragathi Nagar Hyderabad, India -500090
- Telephone：+91 9550333722
SECTION 2: Hazards identification
Classification of the substance or mixture
Not classified.
GHS label elements, including precautionary statements
- Signal word No signal word
none
none
none
none
none
Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
Substance
- Chemical name: Di-''isodecyl'' phthalate
- Common names and synonyms: Di-''isodecyl'' phthalate
- CAS number: 26761-40-0
- EC number: 247-977-1
- Concentration: 100%
SECTION 4: First aid measures
Description of necessary first-aid measures
Fresh air, rest.
Remove contaminated clothes. Rinse skin with plenty of water or shower.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Rest.
Most important symptoms/effects, acute and delayed
No symptoms reported for any rate of exposure. (USCG, 1999)
Indication of immediate medical attention and special treatment needed, if necessary
Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. Esters and related compounds
SECTION 5: Firefighting measures
Suitable extinguishing media
Extinguish with dry chemical, foam or carbon dioxide. Water may be ineffective on fire.
Specific hazards arising from the chemical
This chemical is combustible. (NTP, 1992)
Special protective actions for fire-fighters
Use water spray, powder, alcohol-resistant foam, carbon dioxide.
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Collect leaking and spilled liquid in sealable plastic or metal containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
Environmental precautions
Collect leaking and spilled liquid in sealable plastic or metal containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations.
Methods and materials for containment and cleaning up
ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. For personal protection see section Environmental precautions Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided. Methods and materials for containment and cleaning up Keep in suitable, closed containers for disposal.
SECTION 7: Handling and storage
Precautions for safe handling
NO open flames. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Conditions for safe storage, including any incompatibilities
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage.
SECTION 8: Exposure controls/personal protection
Control parameters
MAK: carcinogen category: 3B
no data available
Appropriate engineering controls
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Individual protection measures, such as personal protective equipment (PPE)
Wear safety goggles.
Protective gloves.
Use ventilation, local exhaust or breathing protection.
no data available
SECTION 9: Physical and chemical properties and safety characteristics
-
Physical state：
Diisodecyl phthalate is a colorless liquid. May float or sink in water. (USCG, 1999)
-
Colour：
Clear liquid
-
Odour：
Mild odor
-
Melting point/freezing point：
-127°C(lit.)
-
Boiling point or initial boiling point and boiling range：
100°C
-
Flammability：
Combustible.
-
Lower and upper explosion limit/flammability limit：
Lower flammable limit: 0.3% by volume at 508 deg F
-
Flash point：
235°C(lit.)
-
Auto-ignition temperature：
755° F (USCG, 1999)
-
Decomposition temperature：
no data available
-
pH：
no data available
-
Kinematic viscosity：
108 cP at 20 deg C
-
Solubility：
Insoluble (NTP, 1992)
-
Partition coefficient n-octanol/water：
log Kow = 10.36 (est)
-
Vapour pressure：
5.63E-10mmHg at 25°C
-
Density and/or relative density：
0.964g/cm3
-
Relative vapour density：
15.4 (NTP, 1992) (Relative to Air)
-
Particle characteristics：
no data available
SECTION 10: Stability and reactivity
Reactivity
Attacks some forms of plastic.
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
CombustibleDIISODECYL PHTHALATE is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Can generate electrostatic charges. [Handling Chemicals Safely 1980. p. 250].
Conditions to avoid
no data available
Incompatible materials
Strong oxidizing agents
Hazardous decomposition products
When heated to decomposition it emits acrid smoke and irritating vapors.
SECTION 11: Toxicological information
Acute toxicity
- Oral: LD50 Rat oral 64 g/kg /64,000 mg/kg/
- Inhalation: LC50 Rat inhalation >12.54 mg/L/4 hr Vestinol DZ
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
The substance is irritating to the eyes and skin.
STOT-repeated exposure
The substance may have effects on the liver.
Aspiration hazard
No indication can be given about the rate at which a harmful concentration of this substance in the air is reached on evaporation at 20°C.
SECTION 12: Ecological information
Toxicity
- Toxicity to fish: LC50; Species: Lepomis macrochirus (Bluegill) juvenile, length 29-40 mm; Conditions: freshwater, static, 22 deg C, pH 7.6-7.9, hardness 25-50 mg/L CaCO3, alkalinity 25-50 mg/L CaCO3; Concentration: 370 ug/L for 96 hr /> or = 95% purity
- Toxicity to daphnia and other aquatic invertebrates: EC50; Species: Daphnia magna (Water flea) age < or =24 hr; Conditions: freshwater, static, 20 deg C, pH 7.6-7.9, hardness 25-50 mg/L CaCO3, alkalinity 25-50 mg/L CaCO3; Concentration: 20 ug/L for 48 hr; Effect: intoxication, immobilization /> or = 95% purity
- Toxicity to algae: EC50; Species: Pseudokirchneriella subcapitata (Green algae); Conditions: freshwater, static, 22-24 deg C, pH 7.6-7.9, hardness 25-50 mg/L CaCO3, alkalinity 25-50 mg/L CaCO3; Concentration: 800 ug/L for 96 hr; Effect: decreased population abundance /> or = 95% purity
- Toxicity to microorganisms: no data available
Persistence and degradability
AEROBIC: In a semi-continuous activated sludge test (Soap and Detergent Association biodegradation test method), the mean degradation for diisodecyl phthalate was 68% in 24 hr(1). In a die-away phase of the testing, it took 9 days to achieve 90% degradation(1). Diisodecyl phthalate is confirmed to be degradable in the screening procedure of the Japanese Ministry of Trade and Industry (MITI) which uses a mixed inoculum derived from soil, fresh water and sewage(2). In an acclimated shake flask CO2 evolution test, loss of parent compound (primary degradation) as well as CO2 evolution (ultimate degradation) was measured using an inoculum prepared from soil and sewage, >99% of diisodecyl phthalate was lost and 56% of theoretical CO2 was evolved after 28 days(3). The biodegradation half-life was 9.6 days with a 4.9 day lag(3). Diisodecyl phthalate, present at 100 mg/L, reached 2% of its theoretical BOD in 2 weeks using an activated sludge inoculum at 30 mg/L in the Japanese MITI test(4). Diisodecyl phthalate, present at a concentration of 100 ppm, was degraded 14 and 30% after three days cultivation in water from the Mino River and Akashi Beach, Japan, respectively(5). Diisodecyl biodegraded 67% from an initial concentration of 48 ppm and 100 ppm in 28 days in activated sludge at 22 and 25 deg C, respectively(6). Diisodecyl phthalate degraded 42% in 21 days at 25 deg C from a starting concentration of 100 ppm(6). An aerobic aquatic half-life of 23 days was given for diisodecyl phthalate(7).
Bioaccumulative potential
BCFs of <3.6 and <14.4 were measured for diisodecyl phthalate at chemical concentrations of 1 and 0.1 mg/L, respectively, using carp (Cyprinus carpio) which were exposed over an 8-week period(1). According to a classification scheme(2), these BCFs suggest that bioconcentration in aquatic organisms is low(SRC). The mean log BCF of diisodecyl phthalate in Daphnia magna as determined in a 21 day test using ring-labeled chemical was 2.06(3), corresponding to a BCF of 115(SRC). The mean log BCF in mussels (Mytilus edulis) was 3.54 between 14 and 28 days also using ring-labeled ester(4), corresponding to a BCF of 3467(SRC). However depuration was rapid in mussels, the half-life being 3.5 days(4).
Mobility in soil
Using a structure estimation method based on molecular connectivity indices(1), the log Koc of diisodecyl phthalate can be estimated to be 6.04(SRC). Other estimated log Koc values reported were 5.46 and 5.78(2). According to a classification scheme(3), these estimated log Koc values suggest that diisodecyl phthalate is expected to be immobile in soil. The average Koc of (14)C-diisodecyl phthalate using three standard USEPA sediments (supplied and characterized by the EPA) was measured at 2.86X10+5(4).
Other adverse effects
no data available
SECTION 13: Disposal considerations
Disposal methods
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
UN Number
ADR/RID: UN2296 (For reference only, please check.)
IMDG: UN2296 (For reference only, please check.)
IATA: UN2296 (For reference only, please check.)
UN Proper Shipping Name
ADR/RID: METHYLCYCLOHEXANE (For reference only, please check.)
IMDG: METHYLCYCLOHEXANE (For reference only, please check.)
IATA: METHYLCYCLOHEXANE (For reference only, please check.)
Transport hazard class(es)
ADR/RID: 3 (For reference only, please check.)
IMDG: 3 (For reference only, please check.)
IATA: 3 (For reference only, please check.)
Packing group, if applicable
ADR/RID: II (For reference only, please check.)
IMDG: II (For reference only, please check.)
IATA: II (For reference only, please check.)
Environmental hazards
ADR/RID: No
IMDG: No
IATA: No
Special precautions for user
no data available
Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
Safety, health and environmental regulations specific for the product in question
SECTION 16: Other information
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/