Oxydiethylene dinitrate SDS

Explosives, Division 1.1

Acute toxicity - Category 2, Oral

Acute toxicity - Category 1, Dermal

Acute toxicity - Category 2, Inhalation

Specific target organ toxicity – repeated exposure, Category 2

Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 3

H201 Explosive; mass explosion hazard

H300 Fatal if swallowed

H310 Fatal in contact with skin

H330 Fatal if inhaled

H373 May cause damage to organs through prolonged or repeated exposure

H412 Harmful to aquatic life with long lasting effects

P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

P230 Keep wetted with ...

P234 Keep only in original packaging.

P240 Ground and bond container and receiving equipment.

P250 Do not subject to grinding/shock/friction/….

P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P264 Wash ... thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P262 Do not get in eyes, on skin, or on clothing.

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P271 Use only outdoors or in a well-ventilated area.

P284 [In case of inadequate ventilation] wear respiratory protection.

P273 Avoid release to the environment.

P370+P372+P380+P373 In case of fire: Explosion risk. Evacuate area. DO NOT fight fire when fire reaches explosives.

P301+P316 IF SWALLOWED: Get emergency medical help immediately.

P321 Specific treatment (see ... on this label).

P330 Rinse mouth.

P302+P352 IF ON SKIN: Wash with plenty of water/...

P316 Get emergency medical help immediately.

P361+P364 Take off immediately all contaminated clothing and wash it before reuse.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P320 Specific treatment is urgent (see ... on this label).

P319 Get medical help if you feel unwell.

P401 Store in accordance with…

P405 Store locked up.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P503 Refer to manufacturer/supplier… for information on disposal/recovery/recycling.

P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.

no data available

Fresh air, rest. Refer for medical attention.

Remove contaminated clothes. Rinse and then wash skin with water and soap. Refer for medical attention .

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Give a slurry of activated charcoal in water to drink. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Refer for medical attention .

Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]: Fire may produce irritating, corrosive and/or toxic gases. (ERG, 2016)

Immediate first aid: Ensure that adequate decontamination has been carried out. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Perform CPR as necessary. Immediately flush contaminated eyes with gently flowing water. Do not induce vomiting. If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain an open airway and prevent aspiration. Keep patient quiet and maintain normal body temperature. Obtain medical attention. Ethylene glycol, glycols, and related compounds

Powder, water spray, foam, carbon dioxide. Note: Evacuate area, fight fires only from an explosion-resistant location ... Cool drums, etc., by spraying with water but avoid contact of the substance with water.

Excerpt from ERG Guide 112 [Explosives* - Division 1.1, 1.2, 1.3 or 1.5]: MAY EXPLODE AND THROW FRAGMENTS 1600 METERS (1 MILE) OR MORE IF FIRE REACHES CARGO. For information on "Compatibility Group" letters, refer to Glossary section. (ERG, 2016)

Use water spray, powder, foam, carbon dioxide. Evacuate area, fight fires only from an explosion-resistant location. In case of fire: keep drums, etc., cool by spraying with water. NO direct contact with water. Combat fire from a sheltered position.

Evacuate danger area! Consult an expert! Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT let this chemical enter the environment. Personal protection: complete protective clothing including self-contained breathing apparatus.

Evacuate danger area! Consult an expert! Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT let this chemical enter the environment. Personal protection: complete protective clothing including self-contained breathing apparatus.

Evacuate danger area! Consult an expert! Collect leaking and spilled liquid in sealable containers as far as possible. Absorb remaining liquid in sand or inert absorbent and remove to safe place. Do NOT let this chemical enter the environment. (Extra personal protection: complete protective clothing including self-contained breathing apparatus.)

NO open flames, NO sparks and NO smoking. Prevent build-up of electrostatic charges (e.g., by grounding). Use non-sparking handtools. Do NOT expose to friction or shock. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.

Fireproof. Store in a separate building. Separated from acids and food and feedstuffs. Cool. Well closed.Fireproof. Store in separate building. Separated from acids, food and feedstuffs . Cool. Well closed.

MAK skin absorption (H)

no data available

Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.

Wear face shield or eye protection in combination with breathing protection.

Protective gloves. Protective clothing.

Use ventilation, local exhaust or breathing protection.

no data available

Heating may cause violent combustion or explosion. May decompose explosively on shock, friction or concussion. On combustion, forms toxic fumes of nitrogen oxides. Reacts with acids.

no data available

A dangerous fire hazard when exposed to heat or flame.As a result of flow, agitation, etc., electrostatic charges can be generated.Nitroorganics, such as DIETHYLENE GLYCOL DINITRATE, range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. Nitroalkanes are milder oxidizing agents, but still react violently with reducing agents at higher temperature and pressures. Nitroalkanes react with inorganic bases to form explosive salts. The presence of metal oxides increases the thermal sensitivity of nitroalkanes. Nitroalkanes with more than one nitro group are generally explosive.

no data available

Can react vigorously with oxidizing or reducing materials.

Upon decomposition it emits toxic fumes of /nitroxides/.

no data available

no data available

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Classification - D; not classifiable as to human carcinogenicity Basis - No human or animal carcinogenic studies found in the available literature. Based on former classification system

no data available

The substance may cause effects on the cardiovascular system, central nervous system and blood. This may result in impaired functions and the formation of methaemoglobin. The effects may be delayed. Medical observation is indicated.

The substance may have effects on the cardiovascular system. This may result in cardiac disorders.

A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20°C.

AEROBIC: Aliphatic nitric acid esters undergo aerobic biodegradation readily via successive removal of nitrate groups to isomeric derivatives. Nitrate esters undergo microbial metabolism by cleaving the nitrate ester group(1). An unspecified amount of diethylene glycol dinitrate was nearly completely degraded in less than 35 days when incubated in diethylene glycol dinitrate-contaminated water enhanced with the addition of yeast and glucose. Degradation in pure water was minimal, suggesting that degradation may occur in acclimated environments(SRC). Loss in combinations of sterile, nonsterile, aerobic and anaerobic river and pond sediments was all within 21 days, suggesting abiotic processes. Degradation in dry soil was slow with 16 and 24% loss after 5 weeks in sterile and nonsterile soil, respectively following the addition of 20 ppm test chemical. Using activated sludge enhanced with mineral salts, oxygen, and ethanol, diethylene glycol dinitrate was shown to degrade by hydrolytic cleavage to porducts including diethylene glycol mononitrate and diethyle glycol(2) and to finally carbon dioxide and methane(3).

An estimated BCF of 3.2 was calculated in fish for diethylene glycol dinitrate(SRC), using a log Kow of 0.98(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).

The Koc of diethylene glycol dinitrate is estimated as 32(SRC), using a log Kow of 0.98(1) and a regression-derived equation(2). According to a classification scheme(3), this estimated Koc value suggests that diethylene glycol dinitrate is expected to have very high mobility in soil. The sorption partition coefficients, Kp, were calculated as 2.3 and 0.8 g/mL for EPA-5 sediment (33.6% sand, 31.0% clay, and 35.4% silt at pH 7.44) and EPA-18 sediment (34.6% sand, 39.5% clay, and 25.8% silt at pH 7.76), respectively; these correspond to Koc values of 100 and 120 g/mL, respectively(1).

no data available

The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.

Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.

ADR/RID: UN0075 (For reference only, please check.)

IMDG: UN0075 (For reference only, please check.)

IATA: UN0075 (For reference only, please check.)

ADR/RID: DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with not less than 25% non-volatile, water-insoluble phlegmatizer, by mass? (For reference only, please check.)

IMDG: DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with not less than 25% non-volatile, water-insoluble phlegmatizer, by mass? (For reference only, please check.)

IATA: DIETHYLENEGLYCOL DINITRATE, DESENSITIZED with not less than 25% non-volatile, water-insoluble phlegmatizer, by mass? (For reference only, please check.)

ADR/RID: 1.1D (For reference only, please check.)

IMDG: 1.1D (For reference only, please check.)

IATA: 1.1D (For reference only, please check.)

ADR/RID: (For reference only, please check.)

IMDG: (For reference only, please check.)

IATA: (For reference only, please check.)

ADR/RID: No

IMDG: No

IATA: No

no data available

no data available

Use of alcoholic beverages enhances the harmful effect.Depending on the degree of exposure, periodic medical examination is suggested.Specific treatment is necessary in case of poisoning with this substance; the appropriate means with instructions must be available.Rinse contaminated clothing with plenty of water because of fire hazard.