Chlorine fluoride SDS
SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifier
- Product name： Chlorine fluoride
- CAS： 7790-89-8
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses： For R&D use only. Not for medicinal, household or other use.
- Uses advised against： none
Company Identification
- Company：Chemicalbook.in
- Address：5 vasavi Layout Basaveswara Nilayam Pragathi Nagar Hyderabad, India -500090
- Telephone：+91 9550333722
SECTION 2: Hazards identification
Classification of the substance or mixture
no data available
GHS label elements, including precautionary statements
- Signal word no data available
no data available
no data available
no data available
no data available
no data available
Other hazards which do not result in classification
no data available
SECTION 3: Composition/information on ingredients
Substance
- Chemical name: Chlorine fluoride
- Common names and synonyms: Chlorine fluoride
- CAS number: 7790-89-8
- EC number: 232-229-9
- Concentration: 100%
SECTION 4: First aid measures
Description of necessary first-aid measures
Fresh air, rest. Half-upright position. Refer for medical attention.
First rinse with plenty of water for at least 15 minutes, then remove contaminated clothes and rinse again. Refer for medical attention .
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms/effects, acute and delayed
no data available
Indication of immediate medical attention and special treatment needed, if necessary
no data available
SECTION 5: Firefighting measures
Suitable extinguishing media
In case of fire in the surroundings, use appropriate extinguishing media.
Specific hazards arising from the chemical
no data available
Special protective actions for fire-fighters
Wear self-contained breathing apparatus for firefighting if necessary.
SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Use personal protective equipment.Wear chemical impermeable gloves. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak.
Environmental precautions
Evacuate danger area! Consult an expert! Personal protection: complete protective clothing SPECIFICALLY RECOMMENDED AS EFFECTIVE AGAINST Chlorine trifluoride, including self-contained breathing apparatus. Ventilation. Turn off gas at source if possible. NEVER direct water jet on liquid.
Methods and materials for containment and cleaning up
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
SECTION 7: Handling and storage
Precautions for safe handling
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Conditions for safe storage, including any incompatibilities
Fireproof. Separated from combustible substances, reducing agents and food and feedstuffs. Cool. Dry.
SECTION 8: Exposure controls/personal protection
Control parameters
no data available
no data available
Appropriate engineering controls
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Individual protection measures, such as personal protective equipment (PPE)
Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US).
Wear fire/flame resistant and impervious clothing. Handle with gloves. Gloves must be inspected prior to use. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.
If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator.
no data available
SECTION 9: Physical and chemical properties and safety characteristics
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Physical state：
NEARLY COLOURLESS COMPRESSED LIQUEFIED GAS WITH CHARACTERISTIC ODOUR.
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Colour：
no data available
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Odour：
no data available
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Melting point/freezing point：
-155.6°C
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Boiling point or initial boiling point and boiling range：
-100°C
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Flammability：
Not combustible but enhances combustion of other substances. Gives off irritating or toxic fumes (or gases) in a fire. Many reactions may cause fire or explosion.
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Lower and upper explosion limit/flammability limit：
no data available
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Flash point：
no data available
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Auto-ignition temperature：
no data available
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Decomposition temperature：
no data available
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pH：
no data available
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Kinematic viscosity：
no data available
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Solubility：
in water: reaction
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Partition coefficient n-octanol/water：
no data available
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Vapour pressure：
1.4 atm
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Density and/or relative density：
1.62 g/cm3
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Relative vapour density：
(air = 1): 3.18
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Particle characteristics：
no data available
SECTION 10: Stability and reactivity
Reactivity
Decomposes above 220°C . This produces toxic gases of chlorine and fluorine compounds. Reacts violently with water and glass. Reacts with all forms of plastics, rubber and resins, except the highly fluorinated polymers. Most combustible materials ignite spontaneously on contact with this substance. Reacts violently with oxidizable materials, metals and metal oxides. Contact with organic materials causes explosion. Contact with acids causes emission of highly toxic fumes.
Chemical stability
no data available
Possibility of hazardous reactions
The gas is heavier than air.
Conditions to avoid
no data available
Incompatible materials
AIR AND WATER REACTIONS: A violent reaction occurs with water or ice generating acidic HF and chlorine, Sidgwick, 1156(1950). The release of Chlorine Trifluoride to the atmosphere rapidly generates two toxic reaction products: HF and Chlorine Dioxide, Lombardi, D.A. and M.D. Cheng 1996. "Modeling Accidental Releases of Chlorine Trifluoride to the Atmosphere," Paper No. 96-WP66B.02, presented at the 89th Annual Meeting of the Air and Waste Management Association, Nashville, Tennessee, June 23-26.CHEMICAL PROFILE: A low-boiling liquid (b.p. 12 C), in gaseous state irritating and toxic. A highly reactive oxidant reagent, spontaneously flammable, used as a rocket propellant. Incompatible with fuels, nitro compounds. Interaction with water is violent and may be explosive, even with ice [ Sidgwick, 1950, p. 1156]. Immediate explosive reaction with hydrocarbons or halocarbons even at -70 C [Brower, K. R., J. Fluorine Chem., 1986, 31, p. 333]. Solution with carbon tetrachloride capable of detonation, solutions with nitroaryl compounds (TNT, hexanitrobiphenyl) or highly chlorinated compounds are extremely shock-sensitive. Violent, sometimes explosive reaction with hydrogen containing materials, e.g., acetic acid, ammonia, benzene, ether, coal gas, hydrogen, hydrogen sulfide, methane, or fluoroamino compounds. Ignition with fibrous materials (cotton, paper, wood). [Mellor, 1956, vol. 2, suppl. 1, p. 155]. Explosive gaseous products (chlorodifluoroamine) formed with ammonium fluoride or ammonium hydrogen fluoride [Gardner, D. M. et al., Inorg., Chem., 1963, 2, p. 413]. Ignition on contact with iodine, boron-containing materials (boron powder, tetraboron carbide, boron-aluminum), fibrous or finaly divided refractory materials (asbestos, glass, wool, sand, tungsten carbide). Violent reaction with mineral acids (nitric acid, sulfuric acid), chromium trioxide, ruthenium metal, selenium tetrafluoride. [Bretherick, 5th ed., 1995, p. 1235]. Chlorine trifluoride is a hypergolic oxidizer and contact with a number of metals and their oxides (aluminum, antimony, arsenic, calcium, copper, iridium, iron, lithium, lead, magnesium, molybdenum, osmium, potassium, rhodium, sodium, selenium, silver, tellurium, tin, tungsten, zinc), nonmetals (phosphorus, silicon, sulfur), salts (mercury iodide, potassium iodide, silver, nitrate, potassium carbonate) will result in a violent reaction often followed by ignition [Mellor, 1956, vol.2, suppl. 1, p. 155; Sidgwick, 1950, p. 1156]. (REACTIVITY, 1999)
Hazardous decomposition products
no data available
SECTION 11: Toxicological information
Acute toxicity
- Oral: no data available
- Inhalation: no data available
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
STOT-single exposure
no data available
STOT-repeated exposure
no data available
Aspiration hazard
no data available
SECTION 12: Ecological information
Toxicity
- Toxicity to fish: no data available
- Toxicity to daphnia and other aquatic invertebrates: no data available
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
Other adverse effects
no data available
SECTION 13: Disposal considerations
Disposal methods
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
SECTION 14: Transport information
UN Number
ADR/RID: UN3310 (For reference only, please check.)
IMDG: UN3310 (For reference only, please check.)
IATA: UN3310 (For reference only, please check.)
UN Proper Shipping Name
ADR/RID: LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. (For reference only, please check.)
IMDG: LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. (For reference only, please check.)
IATA: LIQUEFIED GAS, TOXIC, OXIDIZING, CORROSIVE, N.O.S. (For reference only, please check.)
Transport hazard class(es)
ADR/RID: 2.3 (For reference only, please check.)
IMDG: 2.3 (For reference only, please check.)
IATA: 2.3 (For reference only, please check.)
Packing group, if applicable
ADR/RID: (For reference only, please check.)
IMDG: (For reference only, please check.)
IATA: (For reference only, please check.)
Environmental hazards
ADR/RID: No
IMDG: No
IATA: No
Special precautions for user
no data available
Transport in bulk according to IMO instruments
no data available
SECTION 15: Regulatory information
Safety, health and environmental regulations specific for the product in question
SECTION 16: Other information
Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/