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HomecompanyTri-tert-butylphosphine tetrafluoroborate
Tri-tert-butylphosphine tetrafluoroborate
Tri-tert-butylphosphine tetrafluoroborate
Tri-tert-butylphosphine tetrafluoroborate

Tri-tert-butylphosphine tetrafluoroborate

Price USD1.00
Packge 1KG
  • Min. Order:1G
  • Supply Ability:1MT
  • Time:2019-07-06

Product Details

  • Product NameTri-tert-butylphosphine tetrafluoroborate
  • CAS No.131274-22-1
  • EINECS No.672-603-2
  • MFC12H28P.BF4
  • MW290.13
  • AppearanceCrystals and ChunksWhite
  • Melting point 261 °C(lit.)
  • Water Solubility Soluble in methylene chloride and chloroform. Slightly soluble in terahydro furan. Insoluble in hexane, toluene and water.
  • storage temp. under inert gas (nitrogen or Argon) at 2-8°C

AD68

Tri-tert-butylphosphine tetrafluoroborate Basic information
Reaction
Product Name: Tri-tert-butylphosphine tetrafluoroborate
Synonyms: Tri-t-butylphosphoniumtetrafluoroborate,99%;fluoroboric acid tri-tert-butylphosphine adduct;tri-tert-butylphosphine fluoroboric acid adduct;Tri-tert-butylphosphonium tetrafluoroborate, 97+%;Tri-tert-butylphosphonium tetrafluoroborate,99%;Tri-tert-butylphosphoniuM tetrafluoroborate, 97+% 1GR;Tri-tert-butylphosphine tetrafluoborate;Tri-tert-butylphosphoniuM tetr
CAS: 131274-22-1
MF: C12H28P.BF4
MW: 290.13
EINECS: -0
Product Categories: Ligand;Basic Phosphine LigandsCatalysis and Inorganic Chemistry;Catalysis and Inorganic Chemistry;Cross-Coupling;Phosphine Ligands;Phosphorus Compounds;organometallic complex;Organophosphine salt;Achiral Phosphine;Alkyl Phosphine;P-BF4
Mol File: 131274-22-1.mol
Tri-tert-butylphosphine tetrafluoroborate Structure
 
Tri-tert-butylphosphine tetrafluoroborate Chemical Properties
Melting point  261 °C(lit.)
form  Crystals and Chunks
color  White
Water Solubility  Soluble in methylene chloride and chloroform. Slightly soluble in terahydro furan. Insoluble in hexane, toluene and water.
Sensitive  Hygroscopic
BRN  8813613
InChIKey YSTLBJVHZMEEAC-UHFFFAOYSA-N
CAS DataBase Reference 131274-22-1(CAS DataBase Reference)
 
Safety Information
Hazard Codes  Xn
Risk Statements  36/37/38-20/21/22
Safety Statements  22-24/25-36/37/39-26
RIDADR  UN 1759 8/PG III
WGK Germany  3
HazardClass  8
PackingGroup  III
 
 
Tri-tert-butylphosphine tetrafluoroborate Usage And Synthesis
Reaction
  1. Air-stable, non-pyrophoric precursor of the Tri-t-butylphosphine ligand which is used in a variety of catalytic processes.
  2. Ligand for Suzuki cross-couplings.
  3. Ligand for Heck Reactions.
  4. Ligand for Stille Cross-couplings.
  5. Ligand for α-Arylation and vinylation of arylmandelic acid derivatives.
  6. Ligand for direct arylation of hetercycles
  7. Synthesis of benzocyclobutenes by C-H activation.
  8. Cross-coupling of Grignard reagents and aryl bromides.
  9. Palladium catalyzed annulation of haloanilines.
  10. Palladium-Catalyzed Acylation.
  11. Palladium Catalyzed Carbonylative Heck Reaction.
  12. Palladium-catalyzed aminosulfonylation.
  13. Palladium-catalyzed intramolecular C–O bond formation.
  14. Ruthenium-catalyzed cross-coupling of aldehydes with arylboronic acid.
Chemical Properties white to light yellow crystal powde
Uses suzuki reaction
 
 

Company Profile Introduction

Henan CoreyChem Co., Ltd, based on the original Zhengzhou Cote Chemical Research Institute, be brave in absorbing highly educated talents & overseas returnees; actively responded to Zhengzhou City High-tech Zone Government’s Special Care Policy, reorganized and founded in National University of Science and Technology Park, which is a high-tech, stock enterprise of high-end chemical Custom synthesis;The park was created by the People's Government of Henan Province, and proved by Ministry of Education and the National Science & Technology, taking the construction mode of "many college a park, and common development", mainly depends on Zhengzhou University and Henan University’s scientific research and talent advantage to set up Universities, scientific research institute and enterprise scientific research achievements transformation platform, to make high-tech enterprises incubate,  is the new high-tech talent gathering base, high and new technology industry enterprise radiation base, colleges and universities technological innovation base.
 
Henan Coreychem Co., Ltd, facing global High-tech pharmaceutical raw materials, high complex new type intermediates, fine chemicals custom synthesis, scale-up production and Rare chemicals trade. Corey have well-equipped machine, strong technical force and considerate marketing team service. We also have rich experience advantage in basic research, small scale process development, scale-up, industrial technology development & production and cost control.
 

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career henan chemical co

Henan China
  • Since:2014-12-17
  • Address: No.967,15th Floor,Unit 7, Building 1, No.70 of DianChang Road, High-tech Development Zone, Zhengzho
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