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HomecompanytBuBrettPhos Pd G3
Methanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / t-BuBrettPhos Pd G3
Methanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / t-BuBrettPhos Pd G3

tBuBrettPhos Pd G3

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Packge 10g100g1000g
  • Min. Order:1g
  • Supply Ability:50KG
  • Time:2021-06-11

Product Details

  • Product NameMethanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / t-BuBrettPhos Pd G3
  • CAS No.1536473-72-9
  • MFC44H63NO5PPdS-
  • MW855.433481
  • Appearancesolidbrown-green
  • Melting point 119-131°C
  • storage temp. under inert gas (nitrogen or Argon) at 2-8°C
1536473-72-9
tBuBrettPhos PdG3
Synonym: tert-BuBrettPhos-Pd-G3, 
[(2-Di-tert-butylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate
 
CAS Number: 1536473-72-9
Formula: C44H62NO5PPdS
Formula Weight: 854,43 g/mol
Appearance (Color) White to Very Dark Green to Very Dark
assay  98%
mp  119-131 °C
Caution : air sensitive 
shelf life :12 month 
Supplier: LPBchem-Benjamin
ISO9001 Manufacturer 
Standard laboratory 
ligands catalysts synthesis pharmaceutical compounds electronic intermediates
 
Related Categories
Buchwald 3rd Generation Palladacycles, Buchwald Ligands and Complexes, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling,
Homogeneous Pd Catalysts, Palladium Catalysts
 
General description
tBuBrettPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.
 
Application
tBuBrettPhos Pd G3 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate

Company Profile Introduction

Wuhan LPBchem Technology Co., Ltd, we produce over 50 kinds of palladium catalysts for custom synthesis, especially for the pharmaceutical researching industry.

We are a ISO9001:2005 proved manufacturer, owning a lab more than 1500 squaremeters, consistent of PhD from Top University with many years of experience in China, supplying small to large custom synthesis customers and pharmacy companies, and also exporters around the world with direct bottom quotation and guaranteed quality.

We aimed to help customer's synthesis process, and are glad to create value with customers together.
Email: Benjamin@LPBchem.com WhatsApp:+86-15071314134
Www.LPBchem.com Tel : +86-027-693498399 

 

Our Main products include:
1,1'-Bis(diphenylphosphino)ferrocene palladium(II)dichloride    CAS#72287-26-4
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex     CAS#95464-05-4
Dichlorobis(triphenylphosphine)palladium(II)  CAS#13965-03-2
Tetrakis(triphenylphosphine)palladium(0)  CAS#14221-01-3
Bis(dibenzylideneacetone)palladium   CAS#32005-36-0
Pd2(dba)3/Tris(dibenzylideneacetone)dipalladium  CAS#51364-51-3
Ruphos, Xphos, Xanphos, Cphos, Brettphos Pd series and so on
  • Since:2018-11-29
  • Address: NO.390, HIGH-TECH ROAD, HONGSHAN DISTRICT, WUHAN, HUBEI, CHINA
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