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HomecompanyTris(dibenzylideneacetone)dipalladium(0)-chloroform adduct
Tris(dibenzylideneacetone)dipalladium-chloroform adduct
Tris(dibenzylideneacetone)dipalladium-chloroform adduct

Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct

Price USD10.00USD10.00USD10.00
Packge 10g100g1000g
  • Min. Order:1g
  • Supply Ability:50KG
  • Time:2021-06-11

Product Details

  • Product NameTris(dibenzylideneacetone)dipalladium-chloroform adduct
  • CAS No.52522-40-4
  • EINECS No.610-856-2
  • MFC52H31Cl3O3Pd2
  • MW1023.01
  • InChIKeyWSGMJSHOQWJPPS-UHFFFAOYSA-N
  • AppearanceCrystalline PowderPurple to black
  • storage temp. Keep in dark place,Sealed in dry,Room Temperature
  • Melting point 131-135 °C(lit.)
  • Water Solubility Soluble in organic solvents. Insoluble in water.
52522-40-4
Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct
Synonym: Dipalladium-tris(dibenzylideneacetone)chloroform complex, Pd2(dba)3 · CHCl3
 
CAS Number: 52522-40-4
MDL: MFCD00075479
Formula: C52H43Cl3O3Pd2
Formula Weight: 1,035.10 g/mol
Appearance (Color) Purple to Very Dark Purple and Very Dark
Brown and Black
mp  131-135 °C (lit.)
ISO 9001 MANUFACTURER 
Pharmaceutical compounds OLED intermediates Palladium catalyst
 
Related Categories
Catalysis and Inorganic Chemistry, Chemical Synthesis, Homogeneous Pd Catalysts, Palladium Catalysts
 
General description
Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct (Pd2dba3·CHCl3) is reported to serve as effective precatalysts, or precursors to the active Pd(0) catalyst
 
Application
Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct (Pd2dba3·CHCl3) was used in the following studies:
-To compose the catalytic system for the preparation of homoallylpalladium complexes.These complexes underwent in situ Stille type cross coupling with various vinyltin reagents to afford the cyclized products bearing allyl appendages.
-As palladium source in the asymmetric transformations of 3,4-epoxy-1-butene.
-As catalyst for the Heck cross-coupling reaction of iodobenzene with styrene.
-As cyclization catalyst.
-As catalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes.
-As catalyst for the carbonylation of b,b-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids.

Company Profile Introduction

Wuhan LPBchem Technology Co., Ltd, we produce over 50 kinds of palladium catalysts for custom synthesis, especially for the pharmaceutical researching industry.

We are a ISO9001:2005 proved manufacturer, owning a lab more than 1500 squaremeters, consistent of PhD from Top University with many years of experience in China, supplying small to large custom synthesis customers and pharmacy companies, and also exporters around the world with direct bottom quotation and guaranteed quality.

We aimed to help customer's synthesis process, and are glad to create value with customers together.
Email: Benjamin@LPBchem.com WhatsApp:+86-15071314134
Www.LPBchem.com Tel : +86-027-693498399 

 

Our Main products include:
1,1'-Bis(diphenylphosphino)ferrocene palladium(II)dichloride    CAS#72287-26-4
1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex     CAS#95464-05-4
Dichlorobis(triphenylphosphine)palladium(II)  CAS#13965-03-2
Tetrakis(triphenylphosphine)palladium(0)  CAS#14221-01-3
Bis(dibenzylideneacetone)palladium   CAS#32005-36-0
Pd2(dba)3/Tris(dibenzylideneacetone)dipalladium  CAS#51364-51-3
Ruphos, Xphos, Xanphos, Cphos, Brettphos Pd series and so on
  • Since:2018-11-29
  • Address: NO.390, HIGH-TECH ROAD, HONGSHAN DISTRICT, WUHAN, HUBEI, CHINA
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