Vinylferrocene
- CAS NO.：1271-51-8
- Empirical Formula: C12H12Fe10*
- Molecular Weight: 212.07
- MDL number: MFCD00001434
- EINECS: 215-041-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2025-09-25 17:15:13
What is Vinylferrocene?
Chemical properties
crystalline solid
The Uses of Vinylferrocene
Used in the synthesis of 2-aminomethylferrocenes from vinyl ferrocene and lithium amides.
Definition
ChEBI: Ferrocene substituted on one of the cyclopentadienyl rings by a vinyl group.
Purification Methods
Dissolve vinylferrocene in Et2O, wash it with H2O and brine, dry (Na2SO4), and evaporate to a small volume. Purify it through an Al2O3 (Spence grade H) column by eluting the yellow band with pet ether (b 40-60o). The low melting orange crystals can be sublimed. The tetracyanoethylene adduct crystallises from *C6H6/pentane and has m 137-139o(dec). [Horspool & Sutherland Can J Chem 46 3453 1968, Berger et al. J Org Chem 39 377 1974, Rauch & Siegel J Organomet Chem 11 317 1968, Beilstein 16 III 1787.]
Properties of Vinylferrocene
| Melting point: | 51-53 °C (lit.) |
| Boiling point: | 80-85 °C/0.2 mmHg (lit.) |
| Flash point: | 144 °F |
| storage temp. | Sealed in dry,2-8°C |
| form | crystal |
| color | orange |
| Water Solubility | Insoluble in water. |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
| Exposure limits | ACGIH: TWA 1 mg/m3 NIOSH: TWA 1 mg/m3 |
| Stability: | Stable. Highly flammable. Incompatible with strong acids, strong oxidizing agents. |
| NIST Chemistry Reference | Vinylferrocene(1271-51-8) |
Safety information for Vinylferrocene
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02 |
| GHS Hazard Statements |
H228:Flammable solids |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. |
Computed Descriptors for Vinylferrocene
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