TRIMETHYLSILYLMETHYL AZIDE
- CAS NO.：87576-94-1
- Empirical Formula: C4H11N3Si
- Molecular Weight: 129.24
- MDL number: MFCD00059964
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-05-28 05:09:53
What is TRIMETHYLSILYLMETHYL AZIDE?
Physical properties
bp 43 °C/43 mmHg; IR νmax 2100 cm?1; 1H NMR (CDCl3) δ = 0.12 (s, 9H), 2.75 (s, 2H); MS m/z 129, 73.
The Uses of TRIMETHYLSILYLMETHYL AZIDE
Trimethylsilylmethyl Azide is used in the amination of organometallic compounds; preparation of heterocyclic compounds; precursor of azomethine ylide, reactant in Silylmethyl-Substituted Heterocumulenes and [3 + 2] Cycloaddition etc.
Preparation
Obtained in high yield by reaction of sodium azide and (chloromethyl)trimethylsilane in DMF or HMPA at 80°C.
Properties of TRIMETHYLSILYLMETHYL AZIDE
| Boiling point: | 92-95°C |
| Density | 0,87 g/cm3 |
| refractive index | 1.4300 to 1.4340 |
| Flash point: | 6°C |
| solubility | Sol organic solvents; insol water. |
| form | clear liquid |
| Specific Gravity | 0.87 |
| color | Colorless to Yellow to Green |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
Safety information for TRIMETHYLSILYLMETHYL AZIDE
Computed Descriptors for TRIMETHYLSILYLMETHYL AZIDE
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