MN(TMHD)3
Synonym(s):Mn(dpm)3;Mn(TMHD)3;Shenvi Hydrogenation Catalyst;Tris(dipivaloylmethanato)manganese
- CAS NO.：14324-99-3
- Empirical Formula: C33H57MnO6
- Molecular Weight: 604.74
- MDL number: MFCD00269825
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-01-13 11:20:29
What is MN(TMHD)3?
The Uses of MN(TMHD)3
Catalyst for:
- Intramolecular Diels-Alder reactions
- Single electron donor for excess electron transfer studies in DNA
- Enantioselective synthesis
- Borylation reactions
- Hydrohydrazination and hydroazidation
- Oxidative carbonylation of phenol
Properties of MN(TMHD)3
| Melting point: | 165°C |
| Boiling point: | 255°C |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| form | crystal |
| color | black |
| Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
Safety information for MN(TMHD)3
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for MN(TMHD)3
| InChIKey | ORZPLLPBZHORSD-LWTKGLMZSA-K |
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