METHYL ALPHA-BROMOPHENYLACETATE
- CAS NO.：3042-81-7
- Empirical Formula: C9H9BrO2
- Molecular Weight: 229.07
- MDL number: MFCD00013535
- EINECS: 608-480-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-01-13 11:19:34
What is METHYL ALPHA-BROMOPHENYLACETATE?
Chemical properties
Light yellow to yellow liquid
The Uses of METHYL ALPHA-BROMOPHENYLACETATE
Methyl α-bromophenylacetate may be used as initiator during ESR study of atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) and ethylene glycol dimethacrylate (EGDMA). It may be used as reagent in the homopolymerization of MMA in supercritical carbon dioxide.
Synthesis Reference(s)
Tetrahedron, 42, p. 2275, 1986 DOI: 10.1016/S0040-4020(01)90607-6
General Description
Methyl α-bromophenylacetate is an ester. Palladium catalyzed homocoupling reaction of methyl α-bromophenylacetate with 3,5-dimethyl phenyl boronic acid is reported.
Properties of METHYL ALPHA-BROMOPHENYLACETATE
| Boiling point: | 113 °C3 mm Hg(lit.) |
| Density | 1.46 g/mL at 20 °C(lit.) |
| refractive index | n |
| Flash point: | >230 °F |
| storage temp. | 2-8°C |
| form | clear liquid |
| color | Colorless to Light orange to Yellow |
| BRN | 1102743 |
Safety information for METHYL ALPHA-BROMOPHENYLACETATE
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P363:Wash contaminated clothing before reuse. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. |
Computed Descriptors for METHYL ALPHA-BROMOPHENYLACETATE
| InChIKey | NHFBYYMNJUMVOT-UHFFFAOYSA-N |
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