IRON DODECACARBONYL
- CAS NO.:17685-52-8
- Empirical Formula: C12H24FeO12
- Molecular Weight: 416.15676
- MDL number: MFCD00135617
- EINECS: 241-668-5
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-01-13 11:18:12
What is IRON DODECACARBONYL?
Chemical properties
black powder or crystals
The Uses of IRON DODECACARBONYL
Eliminates sulfur from substituted thiophene complexes, leading to ferroles. Access to new areas of organometallic chemistry is promising using the reaction of Fe3(CO)12 with tellurium-nitrogen heterocycles such as benzoisotellurazole.
The Uses of IRON DODECACARBONYL
It eliminates sulfur from substituted thiophene complexes, which leads to ferroles. Access to new areas of organometallic chemistry is promising using the reaction of Fe3(CO)12 with tellurium-nitrogen heterocycles such as benzoisotellurazole.
General Description
This product has been enhanced for catalytic efficiency.
Purification Methods
It usually contains 10% by weight of MeOH as stabiliser. This can be removed by keeping it in a vacuum at 0.5mm for at least 5hours. It can be sublimed slowly at high vacuum and is soluble in organic solvents. [Landesberg et al. J Org Chem 37 930 1972, Case & Whiting J Chem Soc 4632 1960, King & Stone Inorg Synth VII 193 1963.] TOXIC.
Properties of IRON DODECACARBONYL
| Melting point: | 165 °C (dec.) (lit.) |
| Density | 1.99 |
| Flash point: | 9℃ |
| storage temp. | 2-8°C |
| form | crystal |
| color | black |
| Specific Gravity | 2 |
| Water Solubility | Insoluble in water. Soluble in non polar organic solvents. |
| Sensitive | Air Sensitive |
| Exposure limits | ACGIH: TWA 1 mg/m3 NIOSH: TWA 1 mg/m3 |
| NIST Chemistry Reference | Triiron dodecacarbonyl(17685-52-8) |
Safety information for IRON DODECACARBONYL
| Signal word | Danger |
| Pictogram(s) |
![]() Flame Flammables GHS02 ![]() Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H228:Flammable solids |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P240:Ground/bond container and receiving equipment. P241:Use explosion-proof electrical/ventilating/lighting/…/equipment. P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. |
Computed Descriptors for IRON DODECACARBONYL
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