[Ir(dtbbpy)(ppy)2][PF6]
Synonym(s):[4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine-N1,N1′]bis[2-(2-pyridinyl-N)phenyl-C]iridium(III) hexafluorophosphate;[Ir(dtbbpy)(ppy)2][PF6];Ir Photocatalyst
- CAS NO.：676525-77-2
- Empirical Formula: C40H40F6IrN4P
- Molecular Weight: 913.97
- MDL number: MFCD28369259
- SAFETY DATA SHEET (SDS)
- Update Date: 2025-07-04 15:13:32
![[Ir(dtbbpy)(ppy)2][PF6] Structural](https://img.chemicalbook.in/CAS/20180808/GIF/676525-77-2.gif)
What is [Ir(dtbbpy)(ppy)2][PF6]?
The Uses of [Ir(dtbbpy)(ppy)2][PF6]
[Ir(dtbbpy)(ppy)2]PF6 is an iridium-based photocatalyst which is used to drive various photochemical reactions such as:
- Coupling of N-arylamines and nitroalkanes via an oxidative aza-Henry reaction.
- Atom transfer radical addition (ATRA) of haloalkanes to alkenes and alkynes.
- Conversion of 2-bromoanilides to the corresponding 3,3-disubstituted oxindoles.
- Aryl-alkyl C?C reductive cross-coupling reactions.
Properties of [Ir(dtbbpy)(ppy)2][PF6]
| storage temp. | 2-8°C |
| form | crystal |
| color | yellow |
| λmax | 380nm(CH2Cl2)(lit.) |
Safety information for [Ir(dtbbpy)(ppy)2][PF6]
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. |
Computed Descriptors for [Ir(dtbbpy)(ppy)2][PF6]
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