Dimethyl carbonate
Synonym(s):Carbonic acid dimethyl ester;Dimethyl carbonate;dimethyl ester;DMC;DMC, Methyl carbonate, Carbonic acid dimethyl ester
- CAS NO.:616-38-6
- Empirical Formula: C3H6O3
- Molecular Weight: 90.08
- MDL number: MFCD00008420
- EINECS: 210-478-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-05-30 16:33:02
What is Dimethyl carbonate?
Description
Dimethyl carbonate is a colorless flammable liquid that was originally made by the reaction of 2 moles of methanol with 1 mole of phosgene. But because of phosgene''s extreme toxicity, it is now manufactured by the transesterification of propylene carbonate and methanol or the copper-catalyzed reaction of methanol, oxygen, and carbon monoxide. Dimethyl carbonate is increasingly used as a?methylating agent in place of hazardous, waste-generating compounds, such as dimethyl sulfate and methyl halides.
The Uses of Dimethyl carbonate
Dimethyl carbonate is used as a solvent in organic synthesis and considered as a replacement for solvent like methyl ethyl ketone, tert-butyl acetate and parachlorobenzotrifluoride. It is involved as an intermediate in the preparation of diphenylcarbonate, which in turn is used as a key raw material for the synthesis of Bisphenol-A-polycarbonate. It is also used as a 'green' methylating agent involved in the methylation of aniline, phenols and carboxylic acids. It can be used as a fuel additive due to its high oxygen content. It also finds applications related to supercapacitors and lithium batteries.
Properties of Dimethyl carbonate
Melting point: | 2-4 °C (lit.) |
Boiling point: | 90 °C (lit.) |
Density | 1.069 g/mL at 25 °C (lit.) |
Flash point: | 65 °F |
storage temp. | Store below +30°C. |
solubility | 139g/l |
form | Liquid |
color | <50(APHA) |
Odor | Pleasant |
Water Solubility | 139 g/L |
Sensitive | Moisture Sensitive |
Safety information for Dimethyl carbonate
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 |
GHS Hazard Statements |
H225:Flammable liquids |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P241:Use explosion-proof electrical/ventilating/lighting/…/equipment. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. |
Computed Descriptors for Dimethyl carbonate
InChIKey | IEJIGPNLZYLLBP-UHFFFAOYSA-N |
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