alpha-Ionone
Synonym(s):4-(2,6,6-Trimethyl-2-cyclohexenyl)-3-buten-2-one;alpha-Ionone
- CAS NO.:127-41-3
- Empirical Formula: C13H20O
- Molecular Weight: 192.3
- MDL number: MFCD00001565
- EINECS: 204-841-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-01-13 11:13:54
What is alpha-Ionone?
Description
α-Ionone has a characteristic violet-like odor. α-Ionone may be prepared by condensing citral with acetone to form pseudoionone, which is then cyclized by acid-type reagents.
Chemical properties
clear yellow liquid
Chemical properties
α-Ionone has a warm, woody, berry characteristic violet-like odor. The composition of commercial ionones varies widely in the proportion of α- and β-isomers; the specifications given below refer to the best grade of α- and β-ionones and to a commercial grade that contains both α- and β-ionones.
The Uses of alpha-Ionone
alpha-Ionone, is used in many floral accords. Gives a violet flower nuance to compositions, but is also used in rose, woody, amber, balsamic, and powdery fragrances. It is also used in perfumery, flavoring, and vitamin A (retinol) production for cosmetics and toiletries. beta isomer shows a less floral odor than the alpha. It has good substantivity and is used in all areas of perfumery.
The Uses of alpha-Ionone
An aroma compound commonly found in essential oils such as rose oil. It is a degradation products of caratenoids produced by caratenoid cleavage dioxygenases (CCD).
Definition
ChEBI: Alpha-ionone is an ionone, an enone and a methyl ketone.
General Description
α-lonone is a C13 norterpenoid formed from the degradation of carotenoids. It is an important fragrance compound used in perfume industries due to its characteristic fine violet and rose scents. Commercially α-lonone is used in cosmetics, personal care products, detergents, etc. As a flavoring agent, it is widely used in various beverages including wine and tea.
Flammability and Explosibility
Not classified
Purification Methods
Purify α-ionone through a spinning band fractionating column. The semicarbazone has m 157-157.5o (from EtOH) and [] D +433o (c 4,
Properties of alpha-Ionone
| Melting point: | 25°C |
| Boiling point: | 259-263 °C(lit.) |
| Density | 0.93 g/mL at 25 °C(lit.) |
| vapor pressure | 0.133Pa |
| FEMA | 2594 | ALPHA-IONONE |
| refractive index | n |
| Flash point: | 230 °F |
| storage temp. | 2-8°C |
| solubility | Soluble in ethanol fixed oils, propylene glycol. Slightly soluble in alcohol, ether, mineral oil. |
| form | Oil |
| color | Clear Colourless |
| Odor | at 10.00 % in dipropylene glycol. sweet woody floral violet orris tropical fruity |
| Water Solubility | insoluble |
| Merck | 14,5056 |
| JECFA Number | 388 |
| BRN | 2046084 |
| Dielectric constant | 11.0(18℃) |
| CAS DataBase Reference | 127-41-3(CAS DataBase Reference) |
| NIST Chemistry Reference | 3-Buten-2-one, 4-(2,6,6-trimethyl-2-cyclohexen-1-yl)-, (E)-(127-41-3) |
| EPA Substance Registry System | .alpha.-Ionone (127-41-3) |
Safety information for alpha-Ionone
| Signal word | Danger |
| Pictogram(s) |
![]() Health Hazard GHS08 |
| GHS Hazard Statements |
H334:Sensitisation, respiratory |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P342+P311:IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician. |
Computed Descriptors for alpha-Ionone
alpha-Ionone manufacturer
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