Acetoxyacetic acid
- CAS NO.：13831-30-6
- Empirical Formula: C4H6O4
- Molecular Weight: 118.09
- MDL number: MFCD00011551
- EINECS: 237-541-9
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-04-24 14:58:44
What is Acetoxyacetic acid?
The Uses of Acetoxyacetic acid
Acetoxyacetic acid was used in preparation of tert-butyl glycolate.
General Description
Acetoxyacetic acid is kinetically stable degradation product of oxidative degradation of 1,3-dialkylimidazolium ionic liquids in hydrogen peroxide/aceticacid aqueous medium assisted by ultrasonic chemical irradiation. It is an intermediate formed during reactions of manganic acetate in glacial acetic acid with benzene (100°C), chlorobenzene, or toluene.
Properties of Acetoxyacetic acid
| Melting point: | 67-69 °C (lit.) |
| Boiling point: | 141-142 °C/12 mmHg (lit.) |
| Density | 1.0887 (rough estimate) |
| refractive index | 1.4500 (estimate) |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | Solid |
| pka | 2.69±0.10(Predicted) |
| color | White to Off-White |
| CAS DataBase Reference | 13831-30-6(CAS DataBase Reference) |
| NIST Chemistry Reference | Acetic acid, (acetyloxy)-(13831-30-6) |
Safety information for Acetoxyacetic acid
| Signal word | Danger |
| Pictogram(s) |
 Corrosion Corrosives GHS05 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P363:Wash contaminated clothing before reuse. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for Acetoxyacetic acid
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