5-Chloromethylfurfural
- CAS NO.:1623-88-7
- Empirical Formula: C6H5ClO2
- Molecular Weight: 144.56
- MDL number: MFCD02181084
- EINECS: 216-608-6
- SAFETY DATA SHEET (SDS)
- Update Date: 2025-09-16 17:17:29
What is 5-Chloromethylfurfural?
Chemical properties
Dark Brown Oil
The Uses of 5-Chloromethylfurfural
5-(Chloromethyl)furfural is a lipid oxidation product derived from soybean phospholipids. It is a biofuel precursor in the co-processing of carbohydrates and lipids in oil crops for production of hybrid biodiesel.
What are the applications of Application
5-(Chloromethyl)furfural is a biofuel precursor used to co-process oil crops into biodiesel
What are the applications of Application
5-Chloromethylfurfural is a biofuel that can be made from the reaction of hydrochloric acid and furfural. It is used as a feedstock for the production of 5-hydroxymethylfurfural, which is an important intermediate in the synthesis of many other chemicals. 5-Chloromethylfurfural has been isolated at a yield of 57% from reactions between furfural and chlorine gas. The use of solid catalysts have improved this yield to 68%. It has high chemical stability and can withstand temperatures up to 200°C without decomposition. It also reacts with fatty acids to form amides.
Synthesis Reference(s)
Synthesis, p. 541, 1992 DOI: 10.1055/s-1992-26158
General Description
5-(Chloromethyl) Furfural (CMF) is a potential chemical building block for replacing petroleum-derived chemicals derived from lignocellulosic feedstocks. It is gaining traction as a more practical alternative to 5-(hydroxymethyl)furfural (HMF).
Properties of 5-Chloromethylfurfural
| Melting point: | 37 °C |
| Boiling point: | 137-138 °C(Press: 5 Torr) |
| Density | 1.295±0.06 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,Store in freezer, under -20°C |
| solubility | Chloroform (Slightly), Ethyl Acetate (Slightly) |
| form | Dark Brown to Black Oil to Semi-Solid |
| Stability: | Moisture Sensitive |
| EPA Substance Registry System | 2-Furancarboxyaldehyde, 5-(chloromethyl)- (1623-88-7) |
Safety information for 5-Chloromethylfurfural
| Signal word | Danger |
| Pictogram(s) |
![]() Corrosion Corrosives GHS05 |
| GHS Hazard Statements |
H314:Skin corrosion/irritation |
| Precautionary Statement Codes |
P260:Do not breathe dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P310:Immediately call a POISON CENTER or doctor/physician. P321:Specific treatment (see … on this label). P363:Wash contaminated clothing before reuse. P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. P501:Dispose of contents/container to..… |
Computed Descriptors for 5-Chloromethylfurfural
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