3-(Trifluoromethoxy)bromobenzene
- CAS NO.：2252-44-0
- Empirical Formula: C7H4BrF3O
- Molecular Weight: 241.01
- MDL number: MFCD00040943
- SAFETY DATA SHEET (SDS)
- Update Date: 2025-07-24 18:13:41
What is 3-(Trifluoromethoxy)bromobenzene?
Chemical properties
Clear very faintly yellow liquid
The Uses of 3-(Trifluoromethoxy)bromobenzene
1-Bromo-3-(trifluoromethoxy)benzene may be used in the preparation of 1,2-dehydro-3-(trifluoromethoxy)benzene. It may be used in the synthesis of new electronically deficient atropisomeric diphosphine ligand (S)-CF3O-BiPhep [2,2′-bis(diphenylphosphino)-6,6′-ditrifluoromethoxy-1,1′-biphenyl].
General Description
1-Bromo-3-(trifluoromethoxy)benzene undergoes Diels-Alder reaction with lithium diisopropylamide (LDA) in THF and furan, to yield the corresponding 1,4-dihydro-1,4-epoxy-5- or 6-(trifluoromethoxy)naphthalenes.
Properties of 3-(Trifluoromethoxy)bromobenzene
| Boiling point: | 156-158 °C |
| Density | 1.62 g/mL at 25 °C(lit.) |
| refractive index | n |
| Flash point: | 145 °F |
| storage temp. | Sealed in dry,Room Temperature |
| form | clear liquid |
| color | Colorless to Almost colorless |
| Specific Gravity | 1.64 |
| BRN | 1945938 |
| CAS DataBase Reference | 2252-44-0(CAS DataBase Reference) |
| NIST Chemistry Reference | 3-(Trifluoromethoxy)bromobenzene(2252-44-0) |
Safety information for 3-(Trifluoromethoxy)bromobenzene
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H227:Flammable liquids H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P405:Store locked up. P403+P235:Store in a well-ventilated place. Keep cool. P501:Dispose of contents/container to..… |
Computed Descriptors for 3-(Trifluoromethoxy)bromobenzene
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