(1S)-(+)-(Camphorylsulfonyl)oxaziridine
Synonym(s):(1S)-(+)-(Camphorylsulfonyl)oxaziridine;(1S)-(+)-2,N-Epoxy-exo-10,2-bornanesultam
- CAS NO.：104322-63-6
- Empirical Formula: C10H15NO3S
- Molecular Weight: 229.3
- MDL number: MFCD00075319
- SAFETY DATA SHEET (SDS)
- Update Date: 2026-01-13 11:16:22
What is (1S)-(+)-(Camphorylsulfonyl)oxaziridine?
Chemical properties
(1S)-(+)-(Camphorylsulfonyl)oxaziridine is white crystall powder
The Uses of (1S)-(+)-(Camphorylsulfonyl)oxaziridine
(1S)-(+)-(Camphorylsulfonyl)oxaziridine is a useful synthetic intermediate. Used for asymmetric hydroxylation
The Uses of (1S)-(+)-(Camphorylsulfonyl)oxaziridine
(1S)-(+)-(10-Camphorsulfonyl)oxaziridine can be used:
- To convert prochiral ketone enolates into optically active α-hydroxy ketones via enantioselective asymmetric oxidation.
- In the synthesis of thymidine oligonucleotides connected through pyrophosphates.
- In the asymmetric synthesis of proton pump inhibitors like (R)-Rabeprazole sodium and (R)-Lansoprazole sodium from the corresponding DBU salt of prochiral sulfide.
- In the preparation of phosphonoacetate and thiophosphonoacetate oligodeoxynucleotides by oxidizing the corresponding phosphinoacetate.
What are the applications of Application
(1S)-(+)-(10-Camphorsulfonyl)oxaziridine is a useful Camphor derivative
Properties of (1S)-(+)-(Camphorylsulfonyl)oxaziridine
| Melting point: | 172-174 °C(lit.) |
| Boiling point: | 317.6±25.0 °C(Predicted) |
| alpha | 45 º (c=2, chloroform) |
| Density | 1.2486 (rough estimate) |
| refractive index | 1.5060 (estimate) |
| storage temp. | 2-8°C |
| solubility | Chloroform (Sparingly), Methanol (Slightly) |
| form | Crystals or Crystalline Powder |
| pka | -11.75±0.40(Predicted) |
| color | White |
| optical activity | [α]28/D +45°, c = 2 in chloroform |
| BRN | 6274370 |
| CAS DataBase Reference | 104322-63-6(CAS DataBase Reference) |
Safety information for (1S)-(+)-(Camphorylsulfonyl)oxaziridine
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P271:Use only outdoors or in a well-ventilated area. P280:Wear protective gloves/protective clothing/eye protection/face protection. |
Computed Descriptors for (1S)-(+)-(Camphorylsulfonyl)oxaziridine
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