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506-77-4

506-77-4 structural image
Product Name: Cyanogen chloride
Formula: CClN
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Cyanogen chloride, stabilized appears as a colorless gas or liquid with a strong acrid/pungent odor. Boils at 60 °F. Liquid density 10.0 lb / gal. Shipped as a liquid confined under its own vapor pressure. A highly toxic lachrymator. Has been used as a tear gas. Vapor is heavier than air. Prolonged exposure of the container to fire or intense heat may cause violent rupturing and rocketing.
Color/Form Colorless volatile liquid or gas
Odor Acrid, choking odor
Boiling Point 55.6 °F at 760 mmHg (USCG, 1999)
Melting Point 20 °F (USCG, 1999)
Flash Point Not Applicable. Not flammable. (USCG, 1999)
Solubility 7 % (NIOSH, 2023)
Density 1.222 at 32 °F (USCG, 1999) - Denser than water; will sink
Vapor Density 2.1 (USCG, 1999) - Heavier than air; will sink (Relative to Air)
Vapor Pressure 704.36 mmHg at 50 °F (USCG, 1999)
Stability/Shelf Life Tends to form polymers on storage.
Autoignition Temperature Not Applicable. Not flammable. (USCG, 1999)
Decomposition When heated to decomposition ... it will ... produce highly toxic and corrosive fumes such as /hydrogen chloride, hydrogen cyanide and nitrogen oxides/.
Corrosivity Corrosive
Heat of Vaporization 26.75 kJ/mL
Surface Tension 24.6 dynes/cm = 0.0246 N/m at 10 °C
Ionization Potential 12.49 eV
Polymerization Cyanogen chloride may polymerize violently if contaminated with chlorine.
Odor Threshold Odor Threshold Low: 1.0 [mg/m3] The Guide from the Emergency Response Guidebook is for "cyanogen chloride, inhibited." Detection odor threshold
Relative Evaporation Rate Volatility Rate = 2600 g/cu m at 12.8 C
Other Experimental Properties When heated to decomposition or brought into contact with water or steam, cyanogen chloride produces fumes of chloride ions, cyanide ions and nitrous oxides
Chemical Classes Toxic Gases & Vapors -> Cyanides

COMPUTED DESCRIPTORS

Molecular Weight 61.47 g/mol
XLogP3 1
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 1
Rotatable Bond Count 0
Exact Mass 60.9719267 g/mol
Monoisotopic Mass 60.9719267 g/mol
Topological Polar Surface Area 23.8 Ų
Heavy Atom Count 3
Formal Charge 0
Complexity 31.3
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Cyanogen chloride, stabilized appears as a colorless gas or liquid with a strong acrid/pungent odor. Boils at 60 °F. Liquid density 10.0 lb / gal. Shipped as a liquid confined under its own vapor pressure. A highly toxic lachrymator. Has been used as a tear gas. Vapor is heavier than air. Prolonged exposure of the container to fire or intense heat may cause violent rupturing and rocketing.