CHEMICAL AND PHYSICAL PROPERTIES
| Physical Description | Thiophosgene appears as a reddish liquid. Boiling point 73.5 °C. A severe eye irritant. May severely burn skin on contact. Very toxic by inhalation and by skin absorption. |
|---|---|
| Color/Form | Reddish liquid |
| Odor | Sharp choking odor |
| Boiling Point | 163 °F at 760 mmHg (USCG, 1999) |
| Solubility | Insoluble in water, soluble in ethanol and ethyl ether |
| Density | 1.513 at 68 °F (USCG, 1999) - Denser than water; will sink |
| Vapor Pressure | 116.0 [mmHg] |
| Decomposition | Decomposes above 200 °C to carbon disulfide (very flammable) and carbon tetrachloride. |
| Corrosivity | Corrodes metals in presence of moisture |
| Heat of Combustion | -3,400 BTU/lb= -1,900 cal/g= -80x10+5 J/kg |
| Heat of Vaporization | 128 BTU/lb= 71 cal/g= 3.0x10+5 J/kg |
| Surface Tension | 25 dynes/cm= 0.025 N/m @ 20 °C |
| Refractive Index | Index of refraction: 1.5442 @ 20 °C/D |
| Other Experimental Properties | Decomp in water, alcohol |
| Chemical Classes | Toxic Gases & Vapors -> Other Toxic Gases & Vapors |
SAFETY INFORMATION
| Signal word | Danger |
|---|---|
| Pictogram(s) |
 Corrosion Corrosives GHS05  Skull and Crossbones Acute Toxicity GHS06 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H331:Acute toxicity,inhalation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
COMPUTED DESCRIPTORS
| Molecular Weight | 114.98 g/mol |
|---|---|
| XLogP3 | 2.4 |
| Hydrogen Bond Donor Count | 0 |
| Hydrogen Bond Acceptor Count | 1 |
| Rotatable Bond Count | 0 |
| Exact Mass | 113.9097766 g/mol |
| Monoisotopic Mass | 113.9097766 g/mol |
| Topological Polar Surface Area | 32.1 Ų |
| Heavy Atom Count | 4 |
| Formal Charge | 0 |
| Complexity | 29 |
| Isotope Atom Count | 0 |
| Defined Atom Stereocenter Count | 0 |
| Undefined Atom Stereocenter Count | 0 |
| Defined Bond Stereocenter Count | 0 |
| Undefined Bond Stereocenter Count | 0 |
| Covalently-Bonded Unit Count | 1 |
| Compound Is Canonicalized | Yes |
PRODUCT INTRODUCTION
description
Thiophosgene appears as a reddish liquid. Boiling point 73.5 °C. A severe eye irritant. May severely burn skin on contact. Very toxic by inhalation and by skin absorption.